Production of propylene glycol fatty acid monoesters by lipase-catalyzed reactions in organic solvents |
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Authors: | Jei-Fu Shaw Shian Lo |
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Affiliation: | (1) Institute of Botany, Academia Sinica, Taipei, Taiwan, Republic of China;(2) Institute of Marine Biotechnology, National Taiwan Ocean University, Keelung, Taiwan, Republic of China |
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Abstract: | Fatty acid monoesters of propylene glycol (1,2-propanediol) are good water-in-oil emulsifiers. These esters were synthesized
enzymatically to overcome the problems associated with chemical processes. APseudomonas lipase was added to reaction mixtures containing propylene glycol and various acyl donors (fatty acids, fatty acid ethyl
esters, fatty acid anhydrides and triglycerides) in organic solvents, and the mixtures were shaken at 30°C. The products were
analyzed by gas chromatography. The yield of monoesters was affected by the acyl donors, organic solvents, temperature, water
content, pH memory and reaction time. The anhydrous (lyophilized) enzyme and fatty acid anhydrides were best for monoester
production. The optimum pH ranges were 4–5 and 8–10. The yields of propylene glycol monolaurate, monomyristate, monopalmitate,
monostearate and monooleate with 50 mM fatty acid anhydrides as acyl donors were 97.2, 79.6, 83.7, 89.7 and 93.4 mM, respectively;
those with 50 mM fatty acids as acyl donors were 37.3, 28.7, 28.7, 35.3 and 36.2 mM, respectively. The yields of propylene
glycol monopalmitate, monostearate and monooleate with 50 mM triglycerides as acyl donors were 87.4, 65.1 and 83.2 mM, respectively. |
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Keywords: | Emulsifier enzyme reaction in organic solvent lipase propylene glycol fatty acid monoester |
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