| 水溶性丙烯酸树脂的制备研究 |
| |
| 引用本文： | 林剑雄,王小妹,麦堪成,马宏.水溶性丙烯酸树脂的制备研究[J].中国胶粘剂,2003,12(5):9-11. |
| |
| 作者姓名： | 林剑雄 王小妹 麦堪成 马宏 |
| |
| 作者单位： | 1. 中山大学化学与化学工程学院,广东省广州市,510275
2. 珠江化工集团红云涂料厂,广东省广州市,510515 |
| |
| 摘 要： | 用于水性油墨的水溶性丙烯酸树脂由丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)、丙烯酸(AA)三种单体采用传统的自由基溶液聚合方式合成,通过大量的对比实验筛选了各种不同的反应条件,获得了最佳合成工艺,包括引发剂、溶剂、加料方式、聚合时间和温度。对影响树脂性能的指标如共聚物组成、玻璃化转变温度Tg等各种因素,采用DSC、IR等分析方法进行了详尽的分析和表证。
|
| 关 键 词： | 丙烯酸树脂 水溶性 自由基溶液聚合 水性油墨 |
| 文章编号： | 1004-2849(2003)05-0009-03 |
Synthesis of water-soluble acrylic resin |
| |
| LIN Jian-Xiong,WANG Xiao-Mei,MAI Kan- Cheng,Ma Hong.Synthesis of water-soluble acrylic resin[J].China Adhesives,2003,12(5):9-11. |
| |
| Authors: | LIN Jian-Xiong WANG Xiao-Mei MAI Kan- Cheng Ma Hong |
| |
| Abstract: | The water-soluble acrylic resin which used in water-based inks can be prepared by the conventional free radical solution polymerization, using butyl acrylate ( BA), methyl methacrylate ( MMA ) and acrylic acid ( AA) as monomers. By comparison test, an optimal synthesis technology was obtained, including initiator, solvent, feeding method, polymerization time and temperature. Various factors of influencing the characteristics of the resin, e.g., copolymer composition, glass-transition temperature Tg, were analyzed in detail by various analytical methods, e.g., DSC, IR, as well as chemical methods. |
| |
| Keywords: | acrylic resin free radical solution polymerization water soluble water-based ink |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
