Solvothermal fabrication and luminescent properties of Eu2+/Ce3+ doped barium lithium fluoride |
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作者姓名: | ZHU Guoxian YANG Qu SHI Xiaobo ZHENG Wenzhi LIU Yingliang |
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作者单位: | [1]School of Chemistry Science and Technology and Development Center for New Materials Engineering & Technology in Universities of Guangdong, Zhanjiang Normal University, Zhanjiang 524048, China [2]Department of Chemistry and lnstitute of Nanochemistry, Jinan University, Guangzhou 510632, China |
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基金项目: | Foundation item: Project supported by National Natural Science Foundation of China (U0734005, 20906037), the Ftmdamental Research Funds for the Central Universities (21610102) and the Doctor Special Foundation of Zhanjiang Normal University (ZL 1104) |
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摘 要: | Phosphors of BaLiF3 doped with Eu or/and Ce were solvothermally prepared at 200°C for 5d and characterized by means of X-ray powder diffraction (XRD) and environment scanning electron microscopy (ESEM). The excitation and emission spectra of the rare earth ions doped BaLiF3 were measured by fluorescence spectroscopy and the effects of Ce3+ ions on the luminescence of Eu2+ ions were investigated. In the codoped Eu2+ and Ce3+ system, the emission intensity of Eu2+ ion gradually increased with the Ce3+ concentration increasing, and the enhancement of Eu2+ fluorescence was due to efficient energy transfer from Ce3+ to Eu2+ in the host.
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关 键 词: | BaLiF3 rare earths optical properties solvothermal synthesis |
收稿时间: | 1 December 2011 |
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