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Reactive melt infiltrated Cf/SiC composites with robust matrix derived from novel engineered pyrolytic carbon structure
Affiliation:1. State Key Laboratory of High Performance Ceramics & Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. University of Chinese Academy of Sciences, Beijing 100039, China;1. Analysis and Testing Center, Donghua University, Shanghai 201620, China;2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Shanghai 200050, PR China;3. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics Chinese Academy of Sciences, Shanghai 200050, PR China;1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China;2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;3. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;1. State Key Laboratory of High Performance Ceramics and Super?ne Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;3. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;4. University of Chinese Academy of Sciences, Beijing 100049, China;5. Key Lab of Education Ministry for Power Machinery and Engineering, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Abstract:Needle-punched Cf/SiC composites were fabricated by a novel pore tuned reactive melt infiltration (RMI) process. The novel hierarchically porous carbon structure in the fiber preform with the porosity well open to liquid silicon was engineered by impregnation of phenolic resin with addition of a pore former. Neither residual bulk carbon nor residual bulk silicon is detected in the matrix of the Cf/SiC composites prepared by the pore tuned RMI, indicating that a robust matrix with homogenous SiC can be formed. The composite prepared by the pore tuned RMI exhibits a tensile strength of 159±5 MPa, which is 46% higher than that without addition of pore former.
Keywords:Fibers  Composites  Carbon  SiC
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