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Highly conductive and high-strength carbon nanotube film reinforced silicon carbide composites
Affiliation:1. Science and Technology on Thermostructural Composite Materials Laboratory, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi''an, Shaanxi 710072, PR China;2. School of Science, Xi''an Polytechnic University, Xi''an, Shaanxi 710048, PR China;3. Key Lab of Nanodevices and Applications, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Suzhou 215123, PR China;1. Science and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi?an, Shaanxi 710072, PR China;2. Department of Materials Science and Engineering, University of Ioannina, Ioannina 45110, Greece;3. Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Patras 26504, Greece;4. Department of Chemical Engineering, University of Patras, Rio University Campus, Patras 26504, Greece;1. Science and Technology on Thermostructural Composite Materials Laboratory, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi''an, Shaanxi, 710072, China;2. State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou, 510275, China
Abstract:Film formed by carbon nanotubes is usually called carbon nanotube film (CNTf). In the present study, CNTf fabricated by floating catalyst method was used to prepare CNTf/SiC ceramic matrix composites by chemical vapor infiltration (CVI). Mechanical and electrical properties of the resulting CNTf/SiC composites with different CVI cycles were investigated and discussed, and the results revealed that the CNTf has a good adaptability to CVI method. Tensile test demonstrated an excellent mechanical performance of the composites with highest tensile strength of 646 MPa after 2 CVI cycles, and the strength has a decline after 3 CVI cycles for an excessively dense matrix. While, the elastic modulus of the composite increased with the CVI cycles and reached 301 GPa after 3 CVI cycles. Tensile fracture morphologies of the composites were analyzed by scanning electron microscope to study the performance change laws with the CVI cycles. With SiC ceramic matrix infiltrated into the CNTf, enhanced electrical conductivity of the CNTf/SiC composite compared to pure CNTf was also obtained, from 368 S/cm to 588 S/cm. Conductivity of the SiC matrix with free carbon forming in the CVI process was considered as the reason.
Keywords:Ceramic matrix composites (CMCs)  CNT film  Mechanical property  Electrical property
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