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Mn_(1.18)Cr_(0.02)Fe_(0.8)P_(0.95-x)Ge_xSi_(0.05)化合物的磁热效应
引用本文:哈斯朝鲁,宁君,何小龙,伊日勒图,松林,特古斯,黄焦宏.Mn_(1.18)Cr_(0.02)Fe_(0.8)P_(0.95-x)Ge_xSi_(0.05)化合物的磁热效应[J].磁性材料及器件,2010,41(4):24-26,49.
作者姓名:哈斯朝鲁  宁君  何小龙  伊日勒图  松林  特古斯  黄焦宏
作者单位:1. 内蒙古师范大学内蒙古自治区功能材料物理与化学重点实验室,内蒙古呼和浩特,010022
2. 包头稀土研究院,内蒙古包头,014030
基金项目:国家自然科学基金资助项目,内蒙古自治区自然科学基金重点项目,内蒙古自治区科技规划资助项目 
摘    要:在氩气保护下用高能球磨和粉末烧结法制备了Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05(x=0.245,0.250,0.255,0.260)系列化合物。通过X射线衍射和磁性测量研究了样品的物相结构和磁热效应。该系列化合物结晶为Fe2P型六角结构,少量Si的添加有利于稳定Fe2P型相。热磁曲线显示该系列化合物没有热滞或具有很小的热滞。该系列化合物的居里温度随Ge含量的增加而升高,在0~1.5 T磁场下,最大等温磁熵变约为8J/kg.K。结果说明该系列化合物具有良好的室温磁热效应。

关 键 词:磁热效应  居里温度  磁熵变  热滞

Magnetocaloric Effect in Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05 Compounds
O Haschaolu,NING Jun,HE Xiao-long,S Yiriyoltu,SONG Lin,O Tegus,HUANG Jiao-hong.Magnetocaloric Effect in Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05 Compounds[J].Journal of Magnetic Materials and Devices,2010,41(4):24-26,49.
Authors:O Haschaolu  NING Jun  HE Xiao-long  S Yiriyoltu  SONG Lin  O Tegus  HUANG Jiao-hong
Affiliation:O Haschaolu1,NING Jun1,HE Xiao-long1,S Yiriyoltu1,SONG Lin1,O Tegus1,HUANG Jiao-hong2 1.Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials,Inner Mongolia Normal University,Hohhot 010022,China,2.Baotou Research Institute of Rare Earths,Baotou 014030
Abstract:A series of Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05(x= 0.245,0.250,0.255,0.260) compounds were prepared by high-energy ball milling and solid state reaction under argon atmosphere.The structure and magnetocaloric effect in the compounds were investigated by means of X-ray diffraction and magnetic measurements.The investigated compounds crystallize in the Fe2P-type hexagonal structure,and addition of a small amount of Si is of benefit to stabilizing the Fe2P-type structure.The magnetic measurements showed that the...
Keywords:magnetocaloric effect  Curie temperature  magnetic entropy change  thermal hysteresis  
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