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微乳液法腈纶接枝聚苯胺及其性能研究
引用本文:王新波,王祥荣,王建军.微乳液法腈纶接枝聚苯胺及其性能研究[J].合成技术及应用,2008,23(3).
作者姓名:王新波  王祥荣  王建军
作者单位:1. 苏州大学材料与化学化工学部,江苏,苏州,215123
2. 苏州大学纺织与服装学院,江苏,苏州,215021
摘    要:采用低温等离子体技术对腈纶纤维表面进行处理,使用苯胺微乳液在腈纶表面进行接枝聚合,对腈纶进行改性处理,通过增重率、导电率测试、接枝聚合的因素和接枝聚合对腈纶纤维结构、导电性能和强力进行分析评价;扫描电镜和红外测试显示聚苯胺成功接枝上腈纶表面;腈纶接枝聚苯胺后,导电性能增加,强力变化不大,但伸长率略有降低。

关 键 词:腈纶  苯胺  低温等离子体  接枝聚合  微乳液法  导电性能

Synthesis of acrylic fiber with grafting polyaniline by microemulsion method and its properties
Wang XinBo,Wang XiangRong,Wang JianJun.Synthesis of acrylic fiber with grafting polyaniline by microemulsion method and its properties[J].Synthetic Technology and Application,2008,23(3).
Authors:Wang XinBo  Wang XiangRong  Wang JianJun
Affiliation:Wang XinBo1 Wang XiangRong2 Wang JianJun1 (1.Science Division of Materials and Chemistry & Chemical Engineering; Soochow University; Suzhou Jiangsu 215123; China) (2.College of Textile & Clothes; Suzhou Jiangsu 215021; China);
Abstract:The surface of acrylic fiber was treated by non-thermal plasma technology,so that aniline in microemul- sion was polymerized and grafted on the surface of the fiber.The modified fibers were checked by weight-gain ratio,con- ductivity and grafting polymerization conditions.The structure,electric properties and mechanism of modified fibers were assessed,the results show SEM and FTIR showed that polyaniline was grafted onto the acrylic fiber surface successly;af- ter grafting polyaniline,the electric property of acrylic fiber were improved,tension stregth had little change and the break elongation decreased slight.
Keywords:acrylic fiber  aniline  non-thermal plasma  grafting polymerization  microemulsion method  property
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