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桐酐与甲基四氢苯酐复合固化环氧体系的性能
引用本文:夏建陵,蒋澄,王定选. 桐酐与甲基四氢苯酐复合固化环氧体系的性能[J]. 热固性树脂, 2006, 21(4): 5-8
作者姓名:夏建陵  蒋澄  王定选
作者单位:中国林业科学研究院林产化学工业研究所国家林业局林产化学工程重点开放性实验室,江苏,南京,210042;南京林业大学化学工业学院,江苏,南京,210037
摘    要:研究了不同配比的环氧树脂618/桐酸甲酯酸酐(MeMA)/甲基四氢苯酐(MeTHPA)固化物的固化行为。测定了固化物热变形温度、拉伸强度、弯曲强度、冲击强度及体积电阻等,解析了体系固化前后的红外光谱。结果表明:混合酸酐固化剂中MeTHPA与MeMA的配比为9∶1时,与618环氧树脂固化所得的产物综合性能最佳。2 000 h人工加速老化后其力学性能未见下降。

关 键 词:环氧树脂  甲基四氢苯酐  桐酸甲酯酸酐
文章编号:1002-7432(2006)04-0005-04
收稿时间:2006-02-20
修稿时间:2006-03-18

Study on the properties of curing products of epoxy resin with methyltetrahydrophthalic anhydride and methyl maleieleostearate anhydride
XIA Jan-ling,JIANG Cheng,WANG Ding-xuan. Study on the properties of curing products of epoxy resin with methyltetrahydrophthalic anhydride and methyl maleieleostearate anhydride[J]. Thermosetting Resin, 2006, 21(4): 5-8
Authors:XIA Jan-ling  JIANG Cheng  WANG Ding-xuan
Affiliation:1. Institute of Chemical Industry of Forest Products, CAF, Key and Open Lab on Forest Chemical Engineering, SFA, Nanjing 210042 , China; 2. College of Chemical Engineering, Nanjing Forest University , Nanjing 210037 , China
Abstract:The curing behave of the epoxy resin(618)/methyltetrahydrophthalic anhydride(MeTHPA)/methyl maleieleostearate anhydride(MeMA) systems in different proportion was studied.The heat distortion temperature,peel strength,bending strength,impact strength and volume resistance were measured.FT-IR spectra of the curing system between the beginning and the ending of curing process were compared.It was indicated that the colligated mechanical properties of curing system was best and the volume resistance was tested up to ∞ while ratio of MeTHPA and MEMA was 9∶1 and the curing schedule was 100 ℃×2 h,120 ℃×2 h,140 ℃×5 h.The colligated mechanical properties of curing system did not decreased after 2 000 h accelerated weathering age testing.
Keywords:epoxy resin  methyltetrahydrophthalic anhydride  methyl malei-eleostearate anhydride  
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