Fabricating red-blue-switching dual polymer electrochromic devices using room temperature ionic liquid

In this work, room temperature ionic liquid (RTIL)—1-butyl-3-methyl-imidazolium hexafluorophosphate ([BMIM]PF₆)—was employed to fabricate dual polymer electrochromic devices (DPECDs). [BMIM]PF₆ was used as the electrolyte both in the electrochemical synthesis of conducting polymers (CPs) and in the fabrication of DPECDs. The electrochemically deposited poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(3-methylthiophene) (PMeT) were employed to serve as two complementary coloring electrochromic thin films. Through combining these two electrochromic layers, the assembled DPECDs were found to switch between deep red and deep blue, which are two primary colors for a display. By employing RTIL as electrolyte, the devices retained 65% of their optical contrast and electroactivity after 5×10³ deep double potential steps, showing enhanced stability and durability. The DPECDs also exhibited stable electrochromic performance, with a maximum optical contrast of 26% at 665 nm, and achieved a high coloring efficiency of 460 cm² C^-1.