Electrical properties of a-Si:H thin films as a function of bonding configuration |
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Authors: | Do Yun Kim |
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Affiliation: | School of New Materials Science and Engineering, Yonsei University, 134 Shinchondong, Seodaemungu, Seoul 120-749, Republic of Korea |
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Abstract: | Hydrogenated amorphous silicon (a-Si:H) thin films were fabricated by Radio Frequency (RF) magnetron sputtering. For solar-cell applications, a-Si:H layers are required to show low dark conductivity and high photoconductivity and, thus, high photosensitivity. Hydrogen flow ratio and working pressure were mainly adjusted to control bonding configurations and hydrogen concentration in the films. At a high working pressure of 12 mTorr, all of the prepared amorphous and microcrystalline silicon films showed a dominant IR absorption peak at 2100 cm−1, which indicates a Si-H2 stretching mode, grain boundaries and microvoids. When the working pressure was decreased to as low as 3 mTorr with a hydrogen flow ratio of 0.1, the bonding configuration of the films was mainly Si-H as determined by the dominant IR absorption peak at 2000 cm−1, and the photosensitivity of the films was maximized to 760. |
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Keywords: | Hydrogenated amorphous silicon Bonding configuration Photosensitivity Microvoid Residual strain |
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