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改性A-TiO2紫外光催化降解碱性品红
引用本文:张一兵,肖朵朵.改性A-TiO2紫外光催化降解碱性品红[J].矿冶工程,2013,33(4):116-118.
作者姓名:张一兵  肖朵朵
作者单位:上饶师范学院 化学化工学院, 江西 上饶 334001
基金项目:教育部第四批高等学校特色专业建设点资助项目(TS11524); 江西省高校教学团队资助项目(赣教高字[2008]100号); 江西省省级精品课程资助项目(赣教高字〔2011〕74号)
摘    要:以TiOSO4为原料, 用水热法制备了掺铁TiO2晶体粉末, 用XRD测定了样品的晶型, 研究了以自制的催化剂对碱性品红溶液的光催化降解行为。实验结果表明: 自制的掺铁TiO2为锐钛矿型TiO2(即A-TiO2); 光催化降解碱性品红溶液的优化条件是: 2 mg/L的碱性品红溶液、掺铁量5%(摩尔分数)、A-TiO2粉末加入量1.2 g/L, 室温搅拌下紫外(λ=365 nm)光照降解反应3 h, 此条件下碱性品红溶液降解率达到88.59%。

关 键 词:掺铁A-TiO2  紫外光  光催化  降解  碱性品红  
收稿时间:2013-03-02

Photo-catalystic Degeneration of Fuchsin by Iron-doped Anatase TiO2 under UV-light
ZHANG Yi-bing,XIAO Duo-duo.Photo-catalystic Degeneration of Fuchsin by Iron-doped Anatase TiO2 under UV-light[J].Mining and Metallurgical Engineering,2013,33(4):116-118.
Authors:ZHANG Yi-bing  XIAO Duo-duo
Affiliation:School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao 334001, Jiangxi, China
Abstract:With TiOSO4 as raw materials, iron-doped TiO2 was prepared by hydrothermal method and detected by XRD to characterize its crystal structure. The photo-catalystic degeneration of fuchsin by this catalyst under UV-light was studied. Results show that the crystal structure of as-prepared iron-doped TiO2 is anatase-TiO2 (namely, A-TiO2). With 2 mg/L fuchsin, 5% Fe doping (mole fraction) and a dosage of catalyst A-TiO2 as 1.2 g/L, after being stirred at room temperature, the degeneration rate can be up to 88.59% for fuchsin illuminated by UV-light (365 nm) for 3 h.
Keywords:iron-doped A-TiO2  UV-light  photocatalysis  degradation  fuchsin  
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