| 石灰石和方解石预处理酸性含氟废水的试验研究 |
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| 引用本文： | 张学洪,许立巍,朱义年,王敦球. 石灰石和方解石预处理酸性含氟废水的试验研究[J]. 矿冶工程, 2005, 25(2): 49-52 |
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| 作者姓名： | 张学洪 许立巍 朱义年 王敦球 |
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| 作者单位： | 重庆大学,城市建设与环境工程学院,重庆,400044;桂林工学院,资源与环境工程系,广西,桂林,541004;桂林工学院,资源与环境工程系,广西,桂林,541004 |
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| 基金项目： | 广西壮族自治区教育厅资助项目(桂教科研0240150) |
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| 摘 要： | 稀有金属矿冶炼厂废水成分复杂、酸性强、含氟高、含有多种重金属离子。采用天然石灰石或方解石对其进行中和沉淀预处理, 使pH值升至2.5～3.5, 可以去除大部分氟;然后再投加石灰乳和混凝剂PAM, 使其pH值达8.5 左右, 这样能有效地去除其中的氟和重金属离子。该废水处理工艺形成的化学沉淀少、操作简单方便, 与传统的石灰乳中和法相比, 该工艺能较大幅度地降低酸性废水的处理成本。
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| 关 键 词： | 酸性含氟废水 两步中和 石灰石 方解石 |
| 文章编号： | 0253-6099(2005)02-0049-04 |
| 收稿时间： | 2004-09-05 |
| 修稿时间： | 2004-09-05 |
Utilization of Limestone and Calcite in the Pre-treatment of Acidic Fluoride-containing Wastewater |
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| ZHANG Xue-hong,XU Li-wei,ZHU Yi-nian,WANG Dun-qiu. Utilization of Limestone and Calcite in the Pre-treatment of Acidic Fluoride-containing Wastewater[J]. Mining and Metallurgical Engineering, 2005, 25(2): 49-52 |
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| Authors: | ZHANG Xue-hong XU Li-wei ZHU Yi-nian WANG Dun-qiu |
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| Affiliation: | 1. Faculty of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400044, China;2. Department of Resources and Environmental Engineering, Guilin Institute of Technology, Guilin 541004, Guangxi, China |
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| Abstract: | The industrial wastewater from Rare Metal Refinery is very acidic and contains rich fluoride and various heavy metals.A method of two-step neutralization with the aid of PAM coagulation was used to treat this kind of wastewater.As the first step, natural limestone or calcite was used to neutralize the acid wastewater up to pH =2.5～3.5, and to remove the great mass of fluoride at the same time.Then lime solution was used to adjust pH to 8.5.In this process, fluoride and heavy metals were removed effectively.Compared with the conventional lime neutralization method, this process with little chemical sediment greatly reduces the cost of treating acid wastewater. |
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| Keywords: | acidic fluoride-containing wastewater two-step neutralization limestone calcite |
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