| 微交联丙烯酸酯纳米乳液的制备及应用 |
| |
| 引用本文： | 张静,涂伟萍,夏正斌. 微交联丙烯酸酯纳米乳液的制备及应用[J]. 精细化工, 2005, 22(1): 49-52 |
| |
| 作者姓名： | 张静 涂伟萍 夏正斌 |
| |
| 作者单位： | 华南理工大学,化工与能源学院,广东,广州,510640;华南理工大学,化工与能源学院,广东,广州,510640;华南理工大学,化工与能源学院,广东,广州,510640 |
| |
| 摘 要： | 用半连续种子乳液聚合工艺,合成了微交联丙烯酸酯纳米乳液。讨论了乳化剂、官能性单体、聚合温度及交联改性剂等因素对丙烯酸类聚合物乳液性能的影响。研究结果表明,用本工艺当乳化剂质量分数为2%,N 羟甲基丙烯酰胺质量分数低于0 4%,聚合温度为75～85℃时,可得到平均粒径为49 6nm,多分散性指数为0 149的单峰宽分布丙烯酸酯共聚乳液,将其用于皮革的填充,可显著改善皮革的柔软性、弹性以及革面的手感。
|
| 关 键 词： | 丙烯酸酯 微交联 纳米乳液 皮革填充剂 N-羟甲基丙烯酰胺 |
| 文章编号： | 1003-5214(2005)01-0049-04 |
Development and Application of Slightly Crosslinked Nanophase Acrylate Latex |
| |
| ZHANG jing,TU Wei-ping,XIA Zheng-bin. Development and Application of Slightly Crosslinked Nanophase Acrylate Latex[J]. Fine Chemicals, 2005, 22(1): 49-52 |
| |
| Authors: | ZHANG jing TU Wei-ping XIA Zheng-bin |
| |
| Abstract: | A slightly crosslinked nanophase acrylate latex was synthesized by semicontinuous seeding emulsion polymerization technology.Effect of emulsifier,functional monomer,polymerization temperature and crosslinking agent on the property of acrylate polymer film was discussed.The experimental results indicated that with 2% emulsifiers at 75～85 ℃ and the content of N-(hydroxymethyl)acrylamide lower than 0.4%,the unimodal acrylic emulsion was synthesized,of which the average particle diameter was 49.6 nm and particle distribution was 0.149.The leather filled with this copolymer displayed remarkable improvement in softness,flexibility and fullness. |
| |
| Keywords: | acrylate slightly crosslinked nanophase latex bulking agent of leather N-(hydroxymethyl)-acrylamide |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
