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铁基生物絮凝剂去除废水中的氟和铅
引用本文:苗雨,闵小波,柴立元,尹一男.铁基生物絮凝剂去除废水中的氟和铅[J].中国有色金属学报,2012(8):2366-2373.
作者姓名:苗雨  闵小波  柴立元  尹一男
作者单位:中南大学冶金科学与工程学院;中南大学国家重金属污染防治工程技术中心
基金项目:国家水体污染控制与治理科技重大专项(2009ZX07212-001-01);国家杰出青年科学基金资助项目(50925417);国家高技术研究发展计划重点项目(2010AA065203);新世纪人才计划资助项目(NCET-10-0840)
摘    要:采用自制的铁基生物絮凝剂对废水中氟、铅进行脱除。考察铁基生物絮凝剂投加量、pH、反应时间对F、Pb2+去除效果的影响。结果表明:随铁基生物絮凝剂投加量的增加,F、Pb2+去除率上升;酸性条件有利于F去除率的提高,碱性条件有利于Pb2+去除率的提高;随反应时间的延长,F、Pb2+去除率先上升后下降。在铁基生物絮凝剂投加量为7.5%(体积分数),pH值为6,反应时间为20 min的条件下,F、Pb2+去除率分别为69.75%和99.89%,水中残余F、Pb2+浓度分别为6.05 mg/L和0.226 mg/L,均低于国家《铅、锌工业污染物排放标准》(GB25466—2010)规定的限值。

关 键 词:铁基生物絮凝剂  氟去除  铅去除  废水

Removal of fluoride and lead in wastewater with iron-bioflocculant
MIAO Yu,MIN Xiao-bo,CHAI Li-yuan,YIN Yi-nan.Removal of fluoride and lead in wastewater with iron-bioflocculant[J].The Chinese Journal of Nonferrous Metals,2012(8):2366-2373.
Authors:MIAO Yu  MIN Xiao-bo  CHAI Li-yuan  YIN Yi-nan
Affiliation:1,2 (1.School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China; 2.Chinese National Engineering Research Center to Control and Treatment of Heavy Metal Pollution, Central South University,Changsha 410083,China)
Abstract:Fluoride and lead in the wastewater were removed with self-prepared iron-bioflocculant.The effects of the iron-bioflocculant dosage,pH,reaction time on the removal rate of fluoride and lead were also studied.The results show that the removal rates of F-and Pb2+ increase with the increase of dosage of iron-bioflocculant.F-can be removed more effectively under acidic condition,while alkaline iron solution is good for removing Pb2+.When the reaction time increases,the removal efficiency of F-and Pb2+ rise at the beginning then declines.In addition,the optimum treatment efficiency of the F-and Pb2+ is obtained when dosage is 7.5%(volume fraction),pH value is 6 and reaction time is 20 min.Under these conditions,the removal rates of F-and Pb2+ are 69.75% and 99.89%,respectively,and the residual concentrations of F-and Pb2+ are 6.05 mg/L and 0.226 mg/L,respectively,which are both lower than the emission standards of pollutants for lead and zinc industry at the same time.
Keywords:iron-bioflocculant  fluroide removal  lead removal  wastewater
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