The corrosion of Fe-Mo alloys in H2/H2O/H2S atmospheres |
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Authors: | W Kai D L Douglass F Gesmundo |
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Affiliation: | (1) Department of Materials Science and Engineering, School of Engineering and Applied Science, University of California, 90024-1595 Los Angeles, California;(2) Istituto di Chimica, Facolta di Ingegneria, Universita di Genova, 16219 Genova, Italy |
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Abstract: | The corrosion of Fe-Mo alloys containing up to 40 wt.% Mo was studied over the temperature range 600–980C in a H2/H2O/H2S mixture having a sulfur pressure of 10–5 atm. and an oxygen pressure of 10–20 atm. at 850C. All alloys were two-phase, consisting of an Fe-rich solid solution and an intermetallic compound, Fe3Mo2. The scales formed on Fe-Mo alloys were bilayered, consisting of an outer layer of iron sulfide (FeS) and of a complex inner layer whose composition and microstructure were a function of the reaction temperature and of the Mo content of the alloys. No oxides formed under any conditions. The corrosion kinetics followed the parabolic rate law at all temperatures. The addition of Mo caused only a slight decrease of the corrosion rate. Platinum markers were always located at the interface between the inner and outer scales, indicating that outer scale growth was primarily due to outward diffusion of iron, while the inner scale growth had a contribution from inward diffusion of sulfur. |
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Keywords: | sulfidation Fe-Mo alloys bilayered scales FeMo2S4 Chevrel phase |
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