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The Thermodynamic Property of Rare Earth Complexes with L-Threonine
引用本文:张亚飞,牛春吉,倪嘉缵. The Thermodynamic Property of Rare Earth Complexes with L-Threonine[J]. 中国稀土学报(英文版), 1991, 0(4)
作者姓名:张亚飞  牛春吉  倪嘉缵
作者单位:Changchun Institute of Applied Chemistry Academia Sinica,Changchun 130022,China,Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022,China,Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022,China
基金项目:The Project Supported by NSFC and Lab.of RE Chem.and Phys.
摘    要:In this paper the stability constants and thermodynamic parameters for complexes of rare earth elementswith L-threonine have been measured systematically by potentiometry and calorimetry at 25℃ and ionicstrength of 0.15 mol/L(NaCl).The thermodynamic values for protonation of the anion of L-threonine havebeen obtained.The dependence of stability,enthalpy and entropy change of the complex upon atomic number ofcation is investigated,and the coordination of L-threonine to rare earth is also discussed in detail.


The Thermodynamic Property of Rare Earth Complexes with L-Threonine
Zhang Ya-Fei Niu Chun-Ji Ni Jia-Zan. The Thermodynamic Property of Rare Earth Complexes with L-Threonine[J]. Journal of Rare Earths, 1991, 0(4)
Authors:Zhang Ya-Fei Niu Chun-Ji Ni Jia-Zan
Abstract:
Keywords:Rare earth complex  Threonine  Thermodynamic property
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