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Modification of the surface of polyacrylonitrile fibres before oxidation with a dispersion of technical carbon
Authors:V. N. S'rmadzhieva  P. D. Mikhailova
Affiliation:(1) Bulgaria
Abstract:Conclusions -- The possibility of using dispersions of technical carbon in a medium of ethylene glycol, an aqueous solution of a binder of the ldquoSokrat-binderrdquo type, or an alcoholic solution of polyvinyl butyral for the modification of polyacrylonitrile fibres before thermo-oxidation, which ensure obtaining a stable and uniform carbon-containing film on the fibre surface has been established.-- The use of ethylene glycol as the dispersion medium leads to retention of the strength of fibres after heat treatment at the level of the starting fibres and reduces the specific bulk electrical resistance.-- Application of aqueous solutions of the ldquoSokrat-binderrdquo aids in preserving fibre strength during thermo-oxidation. The linear density of the fibre and its ability to be oxidized are increased, but the specific bulk electrical resistance and elongation are reduced.-- The use of alcoholic solutions of polyvinyl butyral makes it possible not only to preserve fibre strength but also to considerably increase it during the thermo-oxidation process. Thereupon, the linear density of the fibres is significantly reduced, and at a dispersion content of 10% by wt. technical carbon, one can obtain electrically-conducting oxidized fibres.Translated from Khimicheskie Volokna, No. 4, pp. 36–37, July–August, 1991.
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