燃煤O2/CO2循环燃烧过程中SO2与NOx协同脱除的中试研究

由于温室气体影响导致的全球变暖和气候变化日趋严重，温室气体CO2的捕集和封存作为一个缓解气候变化潜在的技术越来越引起全世界的关注。O2/CO2循环燃烧被认为是一种效率高、风险小的CO2捕集方式。该文采用高硫(2.235%)的贫煤，在0.3 MW中试台架上，对O2/CO2、O2/CO2喷钙和O2/CO2循环燃烧喷钙等3种工况进行了SO2和NOx协同脱除的研究。以空气气氛下的燃烧排放作为基准。研究表明：在高CO2气氛下，喷钙脱硫的效率得以显著提高，同时NOx的脱除效率也有明显提高；在O2/CO2 循环燃烧喷钙的工况下，脱硫效率达96%，脱硝效率达89%，尾部烟气中SO2、NOx排放满足国家火电厂大气污染物排放标准的要求。

A Pilot Scale Study on SO2 and NOx Emission Control in O2/CO2 Recycled Coal Combustion

As the global warming and climate change due to greenhouse effects are continuing serious, greenhouse gas CO2 capture and storage (CCS) as a potential option for climate change mitigation has been given the growing worldwide interest. O2/CO2 recycled coal combustion is regarded as an efficient and low-risk CO2 capture method. Three types of experiments: O2/CO2, O2/CO2 with limestone injection and O2/RFG (recycled flue gas) with limestone injection were performed by using high-sulphur lean coal. Combustion in air was performed as a base case. Results show that in high CO2 atmosphere, desulphurization rate of limestone injection can be remarkably increased, simultaneously, denitration rate can also be significantly increased, and in the O2/RFG with limestone injection, desulphurization and denitration rates are 96% and 89% separately. SO2 and NOx emissions are lower than the requirements of Emission Standard of Air Polutants for Thermal Power Plants in China.