| 三嗪类席夫碱分子钳化合物的合成与表征 |
| |
| 引用本文： | 高学祥,赵军龙,李小安,董鑫,花成文,苟小锋. 三嗪类席夫碱分子钳化合物的合成与表征[J]. 应用化工, 2013, 0(12): 2233-2236 |
| |
| 作者姓名： | 高学祥 赵军龙 李小安 董鑫 花成文 苟小锋 |
| |
| 作者单位： | 西北大学化学与材料科学学院合成与天然功能分子化学教育部重点实验室,陕西西安710069 |
| |
| 摘 要： | 以三聚氯氰、二乙胺、香草醛、苯胺、邻甲基苯胺、对溴苯胺和氨基二茂铁为原料,经取代、缩合反应,得到了一类新型的三嗪类钳状席夫碱化合物,并通过IR、1H NMR和元素分析对其结构进行了表征。其紫外研究结果显示,三嗪类席夫碱分子钳化合物T1对Mg2+、Na+有选择性作用;T2对Fe3+有选择性识别作用;T3、T4对Cu2+、Fe3+有选择性作用。
|
| 关 键 词： | 三聚氯氰 席夫碱 分子钳 合成 识别 |
Synthesis and characterization of Schiff base molecular tweezers of 1,3,5-triazine |
| |
| GAO Xue-xiang,ZHAO Jun-long,L,Xiao-an,DONG Xin,HUA Cheng-wen,GOU Xiao-feng. Synthesis and characterization of Schiff base molecular tweezers of 1,3,5-triazine[J]. Applied chemical industry, 2013, 0(12): 2233-2236 |
| |
| Authors: | GAO Xue-xiang ZHAO Jun-long L Xiao-an DONG Xin HUA Cheng-wen GOU Xiao-feng |
| |
| Affiliation: | ( Key Laboratory of Synthetic and Natural Functional Molecule Chemistry ( Ministry of Education) , College of Chemistry and Materials Science, Northwest University, Xi＇an 710069,China) |
| |
| Abstract: | Several clamp-like Schiff base of 1,3,5-triazine were synthesized from cyanuric chloride, dieth ylamine ,vanillin, aniline, o-toluidine, 4-bromoanilines and aminoferrocene by substitution and condensa- tion,and their structures were characterized by IR, 1H NMR and elemental analysis. The studies on the UV-Vis absorption spectroscopies show that Schiff base TI has a selective effect for Mg2, Na ＋ ; T2 has a selective recognition for Fe3＋ ;T3 ,T4 have a selective effect for Cu2＋ ,Fe2＋ |
| |
| Keywords: | cyanuric chloride Schiff base molecular tweezers synthesis recognition |
| 本文献已被 维普 等数据库收录！ |
|
