| 制备条件对氢氧化镁和碱式氯化镁组成和形貌的影响 |
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| 引用本文： | 路绍琰,李先国,王俐聪,张慧峰,吴丹,黄西平,张琦.制备条件对氢氧化镁和碱式氯化镁组成和形貌的影响[J].化工进展,2013,32(4):857-862. |
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| 作者姓名： | 路绍琰 李先国 王俐聪 张慧峰 吴丹 黄西平 张琦 |
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| 作者单位： | 1.国家海洋局天津海水淡化与综合利用研究所，国家海水利用工程技术研究中心，海水化学资源利用技术研究室，天津 300192；2中国海洋大学海洋化学理论与工程技术教育部重点实验室，山东 青岛 266100 |
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| 基金项目： | 国家海洋局青年海洋科学基金(2012553);中央级公益性科研院所基本科研业务费专项资金(K-JBYWF-2011-G22);国家自然科学基金面上项目(21276055) |
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| 摘 要： | 以六水氯化镁和氨水为原料，水热法合成出了氢氧化镁和碱式氯化镁晶须。利用XRD、SEM、TG、FT-IR对产物的组成和形貌进行表征，同时考察了原料浓度、反应温度、反应时间及表面活性剂对产物形貌的影响。结果表明，在低氯化镁浓度和一定氨水滴加量的条件下产物为厚度20～50 nm，具有规则形状的纳米六方片层及其组合玫瑰花球结构的氢氧化镁，增大氯化镁溶液浓度同时减小氨水滴加量产物为直径0.5 μm、长度200 μm的碱式氯化镁单晶。
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| 关 键 词： | 水热法 氢氧化镁 碱式氯化镁 六方片层 玫瑰花球 晶须 |
Influence of preparation conditions on the composition and morphology of magnesium hydroxide and basic magnesium chloride |
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| LU Shaoyan,LI Xianguo,WANGLicong,ZHANG Huifeng,WU Dan,HUANG Xiping,ZHANGQi.Influence of preparation conditions on the composition and morphology of magnesium hydroxide and basic magnesium chloride[J].Chemical Industry and Engineering Progress,2013,32(4):857-862. |
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| Authors: | LU Shaoyan LI Xianguo WANGLicong ZHANG Huifeng WU Dan HUANG Xiping ZHANGQi |
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| Affiliation: | 1Department of Utilizing Chemical Resource from Seawater，Institute of Seawater Desalination and Multipurpose Utilization(SOA)，National Engineering Research Center for Seawater Utilization，Tianjin 300192，China；2Key Laboratory of Marine Chemistry Theory and Technology，Ministry of Education，Ocean University of China，Qingdao 266100，Shandong，China |
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| Abstract: | By using hydrothermal method，the magnesium hydroxide and the basic magnesium chloride whiskers were prepared. XRD，SEM，TG and FT-IR were used to characterize the composition and morphology of the products. The effects of hydrothermal conditions including reactant concentration，reaction temperature，reaction time and surfactant on the morphology were investigated. The results showed that regular hexagonal nano-plates with a thickness of 20—50 nm and the combined rose ball nano-structures of magnesium hydroxide were prepared with low magnesium chloride concentration and a few ammonium hydroxide drops added amount，While the basic magnesium chloride whiskers of 0.5 μm diameter and 200 μm length were single crystall with high magnesium chloride concentration and few ammonium hydroxide drops added amount. |
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| Keywords: | hydrothermal synthesis magnesium hydroxide basic magnesium chloride hexagonal plate rose ball whiskers |
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