The synthesis and catalytic activity to Li/SOCl2 battery of two new porphyrins |
| |
| Affiliation: | 1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi''an, Shaanxi 710069, PR China;2. Wei Nan Teachers University, Wei Nan, Shaanxi 714000, PR China;1. College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310058, China;2. Key Laboratory of On Site Processing Equipment for Agricultural Products, Ministry of Agriculture, Hangzhou 310058, China |
| |
| Abstract: | Two new porphyrins (3a, 3b) were synthesized and characterized by IR, UV–vis, 1H NMR, MS and elementary analysis. The catalytic activity of the synthesized porphyrins to lithium/thionyl chloride (Li/SOCl2) battery is evaluated by the relative energy of the battery whose electrolyte contains the porphyrins. The results indicate that the energy of Li/SOCl2 battery catalyzed by porphyrins 3a and 3b is 101, 37% higher, respectively, than that of Li/SOCl2 battery in the absence of the porphyrins. It can be used as a basis for the synthesis of more porphyrins with improved catalytic activity to Li/SOCl2 battery in the future. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
