Syntheses and characterizations of two-dimensional polymers based on tetraimidazole tetraphenylethylene ligand with aggregation-induced emission property |
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| Affiliation: | 1. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China;2. School of Chemistry and Bioengineering, University of Science and Technology of Suzhou, Suzhou 215009, China;3. Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan;1. College of Science, Nanjing Agricultural University, Nanjing 210095, Jiangsu, China;2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, Jiangsu, China;3. College of Pharmacy, Liaoning Medical University, Jinzhou 121001, Liaoning, China;1. Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, PR China;2. College of Chemistry and Chemical Engineering, Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, Hexi University, Zhangye 734000, PR China;1. State Key Laboratory of Nuclear Resources and Environment, School of Chemistry, Biology and Materials Science, East China University of Technology, Nanchang, 330013, PR China;2. College of Science, Civil Aviation University of China, Tianjin, 300300, PR China;3. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, PR China |
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| Abstract: | Two new coordination polymers [Co(TIPE)(H2O)2]·Hbtc·CH3CN·3H2O (1) and [Cd(TIPE)0.5(m-bdc)(H2O)]·CH3OH·H2O (2) (TIPE = tetra(3-imidazoylphenyl)ethylene, H3btc = 1,3,5-benzenetricarboxylate, m-H2bdc = 1,3-benzenedicarboxylate) have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analysis, IR, TGA, and PXRD. Furthermore, the luminescent properties of complexes 1, 2 and TIPE ligand have also been investigated in the solid at room temperature. |
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