The flexibility of binding modes of the supersilyl thiolate ligand SSitBu3− |
| |
| Affiliation: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, PR China;2. Wuhan Center for Magnetic Resonance, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan 430071, PR China;3. Department of Chemistry and CAS, Panjab University, Chandigarh 160014, India;1. Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;2. Department of Physics, Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani 12120, Thailand;3. Department of Chemistry, Faculty of Science, Thaksin University, Papayom, Phatthalung 93110, Thailand |
| |
| Abstract: | The synthesis and structural characterization of Zn(SSitBu3)2]2 are described. The degradation of sulfur with Zn(SitBu3)2] in tetrahydrofuran yielded the supersilyl thiolate complex Zn(SSitBu3)2]2. X-ray quality crystals of Zn(SSitBu3)2]2 were grown from a benzene solution at ambient temperature (monoclinic, C2/c). The trigonal-planar coordinate zinc atoms in Zn(SSitBu3)2]2 are surrounded by one terminal and two bridging thiolate ligands. The bonds between the Zn and S atoms of the terminal ligands are significantly shorter than those between the Zn and S atoms of the bridging ligands. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
