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Process and mechanical properties of carbon/carbon–silicon carbide composite reinforced with carbon nanotubes grown in situ
Affiliation:1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;3. University of Chinese Academy of Sciences, Beijing 100049, China;1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;3. University of Chinese Academy of Sciences, Beijing 100049, China;1. State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, China;2. Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu 610041, China;1. State Key Laboratory of High Performance Ceramics & Super?ne Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China;2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China;3. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China;4. University of Chinese Academy of Sciences, Beijing, 100039, China;5. ShanghaiTech University, Shanghai, 201210, China;1. Science and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi?an, Shaanxi 710072, PR China;2. Department of Materials Science and Engineering, University of Ioannina, Ioannina 45110, Greece;3. Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Patras 26504, Greece;4. Department of Chemical Engineering, University of Patras, Rio University Campus, Patras 26504, Greece;1. College of Materials & Mineral Resources, Xi?an University of Architecture and Technology, 13#, Yanta Road, Xi’an, Shaanxi 710055, PR China;2. Composite Materials and Structures Laboratory, Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL 32816, USA;3. National Key Laboratory of Thermostructure Composite Materials, Northwestern Polytechnical University, 127#, Youyi Road, Xi’an, Shaanxi 710072, PR China
Abstract:A hierarchical Cf/C–SiC composite was fabricated via in situ growth of carbon nanotubes (CNTs) on fiber cloths following polymer impregnation and pyrolysis process. The effects of CNTs grown in situ on mechanical properties of the composite, such as flexural strength, fracture toughness, crack propagation behavior and interfacial bonding strength, were evaluated. Fiber push-out test showed that the interfacial bonding strength between fiber and matrix was enhanced by CNTs grown in situ. The propagation of cracks into and in fiber bundles was impeded, which results in decreased crack density and a “pull-out of fiber bundle” failure mode. The flexural strength was increased while the fracture toughness was not improved significantly due to the decreased crack density and few interfacial debonding between fiber and matrix, although the local toughness can be improved by the pull-out of CNTs.
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