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Fabrication of microwave exfoliated graphite oxide reinforced thermoplastic polyurethane nanocomposites: Effects of filler on morphology,mechanical, thermal and conductive properties
Affiliation:1. Key Laboratory of Special Materials and Preparation Technologies, College of Materials Science and Engineering, Xi-Hua University, Chengdu, Sichuan 610039, PR China;2. Polymer Engineering Academic Center, Department of Polymer Engineering, University of Akron, Akron, OH 44325-0301, United States;1. Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science & Engineering, Shandong University, Jinan, 250100, PR China;2. Key Laboratory of Colloid & Interface Science of Education Ministry, Shandong University, Jinan, 250100, PR China;1. Faculty of Engineering and Natural Sciences, Sabanci University, Orhanli, 34956 Tuzla, Istanbul, Turkey;2. Sabanci University Nanotechnology Research and Application Center, SUNUM, Orhanli, 34956 Tuzla, Istanbul, Turkey;3. Nanografen Nanotechnological Products Limited Company, GOSB Teknopark, Gebze 41430, Kocaeli, Turkey;1. Key Laboratory of Marine Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo, 315201, China;2. Corrosion & Protection Center, University of Science & Technology Beijing, Beijing, 100083, China;1. Key Laboratory of Functional Nanocomposites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, People’s Republic of China;2. State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, People’s Republic of China;3. School of Aeronautics and Astronautics, Sichuan University, Chengdu 610065, People’s Republic of China
Abstract:Different formulations of microwave-exfoliated graphite oxide (MEGO) based thermoplastic polyurethane (TPU) nanocomposites were successfully prepared via melt blending followed by injection molding. The spectroscopic study indicated that a strong interfacial interaction had developed between the MEGO and the TPU matrix. The microscopic observations showed that the MEGO layers were homogeneously dispersed throughout the TPU matrix. Thermal analysis indicated that the glass transition temperatures (Tg) of the nanocomposites increased with increasing MEGO content and their thermal stability improved in comparison with pure TPU matrix. The mechanical properties of nanocomposites improved substantially by the incorporation of MEGO into the TPU matrix. Electrical conductivity test indicated that a conductivity of 10−4 S cm−1 was achieved in the nanocomposite containing only 4.0 wt.% of MEGO.
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