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Morphology and thermal conductivity of polyacrylate composites containing aluminum/multi-walled carbon nanotubes
Affiliation:1. Department of Polymer Science and Engineering, Kumoh National Institute of Technology, 1 Yangho-dong, Gumi, Gyeongbuk 730-701, Republic of Korea;2. 104, Pohang Techno Park 4th Venture Bldg., 601, Jigok-dong, Nam-gu, Pohang 790-834, Republic of Korea;1. Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;2. College of Electronic and Electrical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China;1. School of Mechanical Engineering, REVA University, Bengaluru, India;2. Department of Mechanical Engineering, National Institute of Technology Karnataka, Surathkal, Karnataka, India;3. Department of Mechanical Engineering, Indian Institute of Technology Palakkad, Kerala, India;1. Department of Oil Application and Management Engineering, Logistical Engineering University, Chongqing 401311, China;;2. Department of Chemistry and Materials Engineering, Logistical Engineering University, Chongqing, 401311, China;;3. Ministry of Supplies and Oil, Chengdu Military Region, Chengdu 610015, China
Abstract:Polyacrylate composites with various fillers such as multi-walled carbon nanotube (CNT), aluminum flake (Al-flake), aluminum powders and Al–CNT were prepared by a ball milling. The thermal decomposition temperature increased by as much as 64 °C for polyacrylate/Al-flake 70 wt% composite compared to polyacrylate. The thermal conductivity of polyacrylate/Al–CNT composites increased from 0.50 to 1.67 W/m K as the Al–CNT content increases from 50 to 80 wt%. The thermal conductivity of the composite sheet increases with the sheet thickness. At the given filler concentration (90 wt%), the composite filled with aluminum powder of 13 μm has a higher thermal conductivity than the one filled 3 μm powder, and the composite filled with mixture of two powders showed a synergistic effect on the thermal conductivity. The morphology indicates that the dispersion of CNT in the polyacrylate/Al-flake + CNT composite is not perfect, and agglomeration of CNTs was observed.
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