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Selectivity dependence on the alloying element of carbon supported Pt-alloy catalysts in the hydrogenation of phenol |
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| Authors: | S.T. Srinivas L. Jhansi Lakshmi P. Kanta Rao |
| Affiliation: | aCatalysis Section, Physical and Inorganic Chemistry Division, Indian Institute of Chemical Technology, Hyderabad-500 007, India |
| Abstract: | Single step vapour phase hydrogenation of phenol over Pt-M/C (M = Cr, V and Zr) alloy catalysts was investigated at atmospheric pressure and 200°C. The alloying element shows a significant effect on the product selectivities. While Pt-Cr/C and Pt-V/C catalysts are highly selective for hydrogenation of phenol to cyclohexanone, the Pt-Zr/C catalysts are predominantly selective to cyclohexanol. |
| Keywords: | alloys phenol hydrogenation platinum selectivity (cyclohexanol/cyclohexanone) |
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