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汽车用增韧尼龙6的热氧老化研究
引用本文:梁惠霞,张东红,张云霄,苗振巍,苑会林.汽车用增韧尼龙6的热氧老化研究[J].工程塑料应用,2009,37(9).
作者姓名:梁惠霞  张东红  张云霄  苗振巍  苑会林
作者单位:1. 石家庄学院化工学院,石家庄,050035
2. 宁波市正邦尼龙有限公司,宁波,315400
3. 北京化工大学材料科学与工程学院,北京,100029
摘    要:分别研究了马来酸酐接枝(乙烯/辛烯)共聚物(POE)、铜盐抗氧剂和受阻酚类抗氧剂1010、1098及其与亚磷酸酯类抗氧剂626复配体系对增韧改性尼龙(PA)6材料抗热氧老化性能的影响,研究了不同抗氧剂体系和热老化时间对材料拉伸强度、简支梁缺口冲击强度的影响。结果表明,在增韧PA6材料中添加合适的抗氧剂可以满足材料在160℃条件下热氧老化24 h后力学性能保持率在90%以上的要求,该材料可以应用于汽车燃油管路系统。

关 键 词:尼龙  热氧老化  增韧  抗氧剂  汽车  

STUDY ON THERMAL OXIDATIVE AGING OF TOUGHENING POLYAMIDE AND APPLIED TO AUTOMOBILE
Liang Huixia,Zhang Donghong,Zhang Yunxiao,Miao Zhenwei,Yuan Huilin.STUDY ON THERMAL OXIDATIVE AGING OF TOUGHENING POLYAMIDE AND APPLIED TO AUTOMOBILE[J].Engineering Plastics Application,2009,37(9).
Authors:Liang Huixia  Zhang Donghong  Zhang Yunxiao  Miao Zhenwei  Yuan Huilin
Affiliation:1.College of Chemical Engineering;Shijiazhuang University;Shijiazhuang 050035;China;2.Zhengbang Nylon Limited Company of Ningbo City;Ningbo 315400;3.School of Material Science and Engineering;Beiing University of Chemical Technology;Beijing 100029;China
Abstract:The effects of maleic anhydride grafted POE, copper oxidation inhibitor, hindered phenolic antioxidants 1010/ 1098 and compounded phosphate antilxidant 626 on the thermal oxidative aging properties of toughening polyamide 6 were studied separately , and the effects of oxidations and aging time on the mechanical properties of polyamide 6 were studied. Experiment results provided that the proper oxidation with polyamide 6 could keep mechanical properties at the rate of 90% above in condition of temperature 160℃ and thermal oxidative for 24 h, and the material could meet requirements of fuel tubes system of automobile.
Keywords:polyamide  thermal oxidative aging  toughening  antioxidant  automobile  
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