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石墨烯橡胶复合改性沥青流变性能及微观性能
引用本文:孟勇军,郭贺源,徐锐光,张瑞杰,马存祥.石墨烯橡胶复合改性沥青流变性能及微观性能[J].建筑材料学报,2020,23(5):1246-1251.
作者姓名:孟勇军  郭贺源  徐锐光  张瑞杰  马存祥
作者单位:广西大学土木建筑工程学院,广西南宁530004;广西大学工程防灾与结构安全教育部重点实验室,广西南宁530004;广西大学土木建筑工程学院,广西南宁530004;广西路桥工程集团有限公司,广西南宁530004
基金项目:国家自然科学基金资助项目(51968006);广西高等教育本科教学改革工程项目(2019JGB100);大学生创新创业训练计划(201910593031)
摘    要:为提高橡胶改性沥青的流变性能,采用动态剪切流变(DSR)试验,对石墨烯掺量不同的石墨烯橡胶复合改性沥青宏观力学性能变化规律进行研究,并结合电动荧光显微镜(E FM)、傅里叶变换红外光谱仪(FTIR),探究石墨烯橡胶复合改性沥青微观结构组成的变化规律.结果表明:与橡胶改性沥青相比,添加石墨烯的橡胶改性沥青具有更高的弹性恢复能力和抗变形能力,其流变性能有所提高;石墨烯橡胶复合改性沥青的荧光显微相态分布均匀且呈连续形貌,说明其存储稳定性和相容性得到了提升;石墨烯橡胶复合改性沥青中芳环CC含量相对增加,说明其力学性能有所提高.

关 键 词:石墨烯  流变性能  动态剪切流变试验  电动荧光显微镜  傅里叶变换红外光谱仪
收稿时间:2019/5/20 0:00:00
修稿时间:2019/8/15 0:00:00

Rheological and Microscopic Properties of Graphene Rubber Composite Modified Asphalt
MENG Yongjun,GUO Heyuan,XU Ruiguang,ZHANG Ruijie,MA Cunxiang.Rheological and Microscopic Properties of Graphene Rubber Composite Modified Asphalt[J].Journal of Building Materials,2020,23(5):1246-1251.
Authors:MENG Yongjun  GUO Heyuan  XU Ruiguang  ZHANG Ruijie  MA Cunxiang
Affiliation:College of Civil Engineering and Architecture, Guangxi University, Nanning 530004, China; Guangxi Road and Bridge Engineering Group Co., Ltd., Nanning 530004, China
Abstract:In order to improve the rheological properties of rubber modified asphalt, the feasibility of graphene rubber composite modified asphalt was studied. Dynamic shear rheological(DSR) test combined with electrodynamic fluorescence microscopy(E FM) and Fourier transform infrared spectrometer(FTIR) was used to study the macro mechanical properties of graphene rubber modified asphalt with different content of graphene, FTIR was used to investigate the change of the microstructure of rubber modified asphalt. The results show that the addition of graphene can improve the elastic recovery and deformation resistance of rubber modified asphalt, and improve its rheological properties. The fluorescence microscopy of graphene rubber composite modified asphalt shows uniform distribution and continuous morphology in the electro fluorescence microscope, which indicates that the storage stability of rubber modified asphalt is improved. In infrared spectroscopy, the addition of graphene makes rubber and asphalt more compatible. The relative increase of CC content indicates that its mechanical properties are improved.
Keywords:graphene  rheological property  dynamic shear rheological test  electrodynamic fluorescence microscopy  Fourier transform infrared spectroscopy
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