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铝阳极氧化膜绿色封闭工艺
引用本文:田连朋,左禹,施惠基.铝阳极氧化膜绿色封闭工艺[J].腐蚀与防护,2007,28(8):414-416.
作者姓名:田连朋  左禹  施惠基
作者单位:1. 清华大学航天航空学院工程力学系,北京,100084
2. 北京化工大学材料科学与工程学院,北京,100029
基金项目:国家自然科学基金资助项目(10472049)
摘    要:探索了新的不含有害物质的铝合金阳极氧化膜绿色封闭技术;新方法使用了铈盐化学处理和钼盐溶液电化学处理相结合的工艺。对比了不同封闭方法对L3铝合金阳极氧化膜在NaCl溶液中耐蚀性的影响,包括氟化镍封闭,重铬酸钾封闭和铈-钼盐封闭。利用动电位极化法研究了封闭后阳极氧化膜的腐蚀行为。利用扫描电子显微镜(SEM)观察了封闭后阳极氧化膜的表面形貌和成分。结果表明铈-钼盐封闭工艺可以为铝合金阳极氧化膜在NaCl溶液中提供较高的耐蚀性。

关 键 词:L3铝合金  阳极氧化  封闭
文章编号:1005-748X(2007)08-0414-03
收稿时间:2006-09-14
修稿时间:2006-09-14

GREEN SEALING METHOD OF ANODIC ALUMINA FILMS
TIAN Lian-peng,ZUO Yu,SHI Hui-Ji.GREEN SEALING METHOD OF ANODIC ALUMINA FILMS[J].Corrosion & Protection,2007,28(8):414-416.
Authors:TIAN Lian-peng  ZUO Yu  SHI Hui-Ji
Affiliation:1. Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China; 2. School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:A green sealing method of anodic films on aluminum alloy L3 was studied to eliminate the toxic materials.The new process uses chemical treatments in cerium solution and an electrochemical treatment in a molybdate solution.Potentiodynamic polarization was used to study the influences of sealing methods on the corrosion behavior of anodic films in NaCl solutions.The Ce-Mo sealing made the surface structure and morphology of anodic films uniform and compact.Ce and Mo produced a cooperative effect to improve the corrosion resistance of anodic films.Anodic films sealed by Ce-Mo provided high corrosion resistance in NaCl solutions.
Keywords:Aluminum alloy L3  Anodic film  Sealing
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