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Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions
作者姓名:Wu Dengguo  Sun Yuanhong  Li Guozhu
作者单位:Department of Chemistry,Inner Mongolia University,Hohhot 010021,China
摘    要:EfectofDiferentLigandFieldStrengthsontheOscilatorStrengthsofLanthanideIonsWuDengguo(武登国),SunYuanhong(孙元洪),LiGuozhu(李国柱)(Depar...

关 键 词:Rare  earths  Rare  earth  complexes

Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions
Wu Dengguo,Sun Yuanhong,Li Guozhu.Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions[J].Journal of Rare Earths,1998,16(1):5-9.
Abstract:The oscillator strengths of the absorption spectra for rare earth complexes in different solvents were determined and calculated on the basis of the Judd-Ofelt theory. The effect of different ligand field strengths on the oscillator strengths of lanthanide ions is discussed. In plotting the oscillator strengths of the hypersensitive transition of Ho3+, Er3+ against those of Nd3+, the reverse extending lines of the straight lines were found to intersect at a point on the whole. The coordinates of the crosspoint are believed to represent the strength value of the smallest coordinated effect.
Keywords:Rare earths  Rare earth complexes  Hypersensitive transitions  Oscillator strength
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