Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions |
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引用本文: | Wu Dengguo,Sun Yuanhong,Li Guozhu. Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions[J]. 中国稀土学报(英文版), 1998, 16(1): 5-9 |
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作者姓名: | Wu Dengguo Sun Yuanhong Li Guozhu |
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作者单位: | Department of Chemistry,Inner Mongolia University,Hohhot 010021,China |
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摘 要: | EfectofDiferentLigandFieldStrengthsontheOscilatorStrengthsofLanthanideIonsWuDengguo(武登国),SunYuanhong(孙元洪),LiGuozhu(李国柱)(Depar...
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关 键 词: | Rare earths Rare earth complexes |
Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions |
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Abstract: | The oscillator strengths of the absorption spectra for rare earth complexes in different solvents were determined and calculated on the basis of the Judd-Ofelt theory. The effect of different ligand field strengths on the oscillator strengths of lanthanide ions is discussed. In plotting the oscillator strengths of the hypersensitive transition of Ho3+, Er3+ against those of Nd3+, the reverse extending lines of the straight lines were found to intersect at a point on the whole. The coordinates of the crosspoint are believed to represent the strength value of the smallest coordinated effect. |
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Keywords: | Rare earths Rare earth complexes Hypersensitive transitions Oscillator strength |
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