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Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions
引用本文:Wu Dengguo,Sun Yuanhong,Li Guozhu. Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions[J]. 中国稀土学报(英文版), 1998, 16(1): 5-9
作者姓名:Wu Dengguo  Sun Yuanhong  Li Guozhu
作者单位:Department of Chemistry,Inner Mongolia University,Hohhot 010021,China
摘    要:EfectofDiferentLigandFieldStrengthsontheOscilatorStrengthsofLanthanideIonsWuDengguo(武登国),SunYuanhong(孙元洪),LiGuozhu(李国柱)(Depar...

关 键 词:Rare earths  Rare earth complexes

Effect of Different Ligand Field Strengths on the Oscillator Strengths of Lanthanide Ions
Abstract:The oscillator strengths of the absorption spectra for rare earth complexes in different solvents were determined and calculated on the basis of the Judd-Ofelt theory. The effect of different ligand field strengths on the oscillator strengths of lanthanide ions is discussed. In plotting the oscillator strengths of the hypersensitive transition of Ho3+, Er3+ against those of Nd3+, the reverse extending lines of the straight lines were found to intersect at a point on the whole. The coordinates of the crosspoint are believed to represent the strength value of the smallest coordinated effect.
Keywords:Rare earths   Rare earth complexes   Hypersensitive transitions   Oscillator strength
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