| X射线荧光光谱法测定冶炼锡烟尘中10个组分 |
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| 引用本文： | 陈林,贺与平. X射线荧光光谱法测定冶炼锡烟尘中10个组分[J]. 冶金分析, 2007, 27(5): 1-1 |
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| 作者姓名： | 陈林 贺与平 |
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| 作者单位： | 云锡股份有限公司冶炼分公司,昆明理工大学分析测试研究中心 云南个旧 661000,云南昆明 650051 |
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| 摘 要： | 采用硼酸衬底直接压片法制取锡冶炼烟尘粉末的片状试样,然后用X射线荧光光谱法测定烟尘试样中Al_2O_3,As,SiO_2,Fe_2O_3,CaO,MgO,Pb,S,Sn,Zn含量。元素之间谱线干扰采用ARL9400WinXPF 2.0软件中的Trail-Lachance模型进行校正。对一样品的各组分进行11次测定,得到相对标准偏差在0.09%～3.66%之间,测定结果与滴定法和原子吸收光谱法吻合较好。方法快速、准确,可满足生产快速分析的要求。
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| 关 键 词： | X射线荧光光谱法 粉末直接压片 锡烟尘 |
| 文章编号： | 1000-7571（2007）05-0059-03 |
| 修稿时间： | 2006-04-30 |
Determination of ten Components in flue dust during tin making by X-ray fluorescence spectrometry |
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| CHEN Lin,HE Yu-ping. Determination of ten Components in flue dust during tin making by X-ray fluorescence spectrometry[J]. Metallurgical Analysis, 2007, 27(5): 1-1 |
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| Authors: | CHEN Lin HE Yu-ping |
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| Abstract: | A method for direct determination of Al_2 O_3,As,SiO_2,Fe_2 O_3,CaO,MgO,Pb,S,Sn,Zn in flue dust during tin making is developed.The powder sample was pressed into a pellet in a mould lined with boric acid,then all kinds of component in the pellet were determined by X-ray fluorescence spec- trometry.Traill-Lachance correction model of the software ARL 9400 win XRF was applied for correc- ting spectral interefere of elements.The determination results of this method coincide with that of AAS(or titrimetry),demonstrating the accuracy of method.The relative standard deviation(n=11) was from 0.09% to 3.66%. |
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| Keywords: | X-ray fluorescence spectrometry pressed powder pellet flue dust of tin. |
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