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Synthesis and Luminescence Properties of Gd_2O_3∶Eu~(3+) Phosphors
引用本文:李艳红,刘桂霞,洪广言.Synthesis and Luminescence Properties of Gd_2O_3∶Eu~(3+) Phosphors[J].中国稀土学报(英文版),2004,22(1).
作者姓名:李艳红  刘桂霞  洪广言
作者单位:Key Laboratory of Rare Earth Chemistry and Physics,Key Laboratory of Rare Earth Chemistry and Physics,Key Laboratory of Rare Earth Chemistry and Physics Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China,College of Materials and Chemical Engineering,Changchun University of Science and Technology,Changchun 130022,China,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChina ( 2 0 0 710 3 1)
摘    要:Gd2 O3∶Eu3+ isanefficientredemittinglumines centmaterial ,whichcanbeappliedindisplays1,2 ] .TheconventionalcommercialGd2 O3∶Eu3+ ismainlysynthesizedbyhightemperaturesolid statereactionandchemicalco precipitationmethods .Anadvancedperformanceofdisplaysrequireshighqualityphospho rssuchashighbrightnessandefficiency ,monodisper sityandfinegrainsize .Muchresearchhasanticipatedthatsubmicrometer sizedandnanometerluminescentmaterialswillhavethesepotentialadvantages3~ 8] ,sosubmicrometer sizedan…

关 键 词:optics  Gd  2O  3∶Eu  3+  phosphors  urea  homogeneous  precipitation  sol-gel  method  luminescence  spectra  rare  earths

Synthesis and Luminescence Properties of Gd2O3∶Eu3+ Phosphors
Li Yanhong ,Liu Guixia ,Hong Guangyan.Synthesis and Luminescence Properties of Gd2O3∶Eu3+ Phosphors[J].Journal of Rare Earths,2004,22(1).
Authors:Li Yanhong    Liu Guixia  Hong Guangyan
Affiliation:Li Yanhong 1,2,Liu Guixia 1,Hong Guangyan 1*
Abstract:Gd2O3∶Eu3+ phosphors were prepared by urea homogeneous precipitation with different surfactant and sol-gel method. XRD patterns show that all the obtained samples are in cubic Gd2O3, and the results of FTIR and fluorescent spectra conformed that OP is a good surfactant for preparing the Gd2O3∶Eu3+ phosphors. The SEM photographs show that the particles prepared by urea homogeneous precipitation method are all spherical and well-dispersed, and grain morphology can be controlled by different surfactant. XRD and SEM indicate that the particle sizes prepared by sol-gel method are in the range of 5~30 nm, and the grain sizes increase with increasing of heated temperatures. Luminescence spectra indicat that the main emission peaks of all samples are at 610 nm, the intensities are different from samples prepared with different surfactant and the luminescence intensities increase with increasing of annealed temperatures.
Keywords:optics  urea homogeneous precipitation  sol-gel method  luminescence spectra  rare earths
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