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脉冲参数对磺基水杨酸镀液镀银性能的影响
引用本文:田洪丽,于锦,单颖会.脉冲参数对磺基水杨酸镀液镀银性能的影响[J].电镀与精饰,2009,31(9).
作者姓名:田洪丽  于锦  单颖会
作者单位:沈阳工业大学,理学院,辽宁,沈阳,110123
摘    要:以硝酸银为主盐,磺基水杨酸为络合剂,醋酸铵和氨水为pH调节剂.研究了平均电流密度、脉冲宽度、占空比、溶液pH对镀层以及抗变色性能的影响;利用X-射线衍射分析研究了镀层结构.实验结果表明:常温下Jm=0.3 ~ 0.5 A/dm2,脉冲宽度为0.1 ~ 4 ms,占空比为5% ~ 25%,pH=8.8 ~ 9.3时,可以获得结合紧密、光亮细致的银镀层,且抗变色性能及耐腐蚀性均增强;X-射线衍射分析显示镀层主要成分是Ag.

关 键 词:脉冲参数  磺基水杨酸  无氰镀银  抗变色性

Effects of Pulse Parameters on Silver Plating Properties of Sulfosalicylic Acid Silver Electroplating Bath
TIAN Hong-li,YU Jin,SHAN Ying-hui.Effects of Pulse Parameters on Silver Plating Properties of Sulfosalicylic Acid Silver Electroplating Bath[J].Plating & Finishing,2009,31(9).
Authors:TIAN Hong-li  YU Jin  SHAN Ying-hui
Affiliation:TIAN Hong-li,YU Jin,SHAN Ying-hui(School of Science,Shenyang University of Technology,Shenyang 110023,China)
Abstract:With silver nitrate as main salts,sulfosalicylic acid as complexant,ammonium acetate and ammonia as pH regulator,the effects of average current density,pulse width,duty cycle and solution acidity on electroplating property and anti-tarnish property were investigated.The structure of coating were analyzed by X-ray diffraction(XRD).The results showed that the compact,bright and uniform coating,with stronger anti-tarnish property and corrosion resistance,can be obtained under the conditions of average current ...
Keywords:pulse parameters  sulfosalicylic acid  non-cyanide silver electroplating  anti-tarnish property  
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