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Poly(vinylidene fluoride)/poly(methyl methacrylate)/TiO2 blown films: preparation and surface study
Authors:Weihua Tang  Tiange Zhu  Peipei Zhou  Wei Zhao  Qian Wang  Gang Feng and Huilin Yuan
Affiliation:(1) Key Laboratory of Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China;(2) Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China
Abstract:Blown films of poly(vinylidene fluoride) (PVDF) and poly(methyl methacrylate) (PMMA) blends and PVDF/PMMA/TiO2 composites were prepared by melting-extrusion for the first time. The crystalline structure and surface morphology PVDF/PMMA (DFMA) blown films were investigated using differential scanning calorimeter (DSC), atomic force microscope (AFM), and X-ray diffractometry (XRD). PVDF/PMMA/TiO2 blown films were further prepared and underwent surface treatment. The results show that PVDF/PMMA/TiO2 blown films present good mechanical properties, and acrylic acid surface-grafted films exhibit good adhesion capability and long-lasting hydrophilicity, making them attractive as encapsulation materials.
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