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Vanadium peroxocomplexes as oxidation catalysts of sulfur organic compounds by hydrogen peroxide in bi-phase systems |
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| Authors: | Alexander V. Anisimov Elena V. Fedorova Andrey Z. Lesnugin Vladimir M. Senyavin Leonid A. Aslanov Viktor B. Rybakov Alla V. Tarakanova |
| Affiliation: | Department of Chemistry, Moscow State University, Moscow 119899, Russia |
| Abstract: | New vanadium oxodiperoxocomplexes Bu4N+[VO(O2)2 L2]− were synthesized, where L=pyridine (1), 2-methylpyridine (2), 4-methylpyridine (3), 2-oxymethylpyridine (4). All complexes were characterized by NMR (1H, 51V) and IR spectroscopy. The oxidation of sulfur organic compounds and diesel fuel desulfurization catalyzed by vanadium peroxocomplexes in bi-phase system was investigated in various solvents. The complexes manifested high catalytic activity and selectivity in oxidation of sulfides. |
| Keywords: | Vanadium Oxidation Oxodiperoxocomplexes Pyridine ligands Bi-phase catalysis |
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