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SMAH对PA6/ABS合金的增容作用研究
引用本文:张凯舟,秦舒浩,于杰.SMAH对PA6/ABS合金的增容作用研究[J].工程塑料应用,2007,35(12):22-25.
作者姓名:张凯舟  秦舒浩  于杰
作者单位:国家复合改性聚合物材料工程技术研究中心,贵阳,550014
基金项目:贵州省“十一五”重大专项(黔科合重大专项字[2006]6033)
摘    要:研究了(苯乙烯/马来酸酐)共聚物(SMAH)对尼龙(PA)6/(丙烯腈/丁二烯/苯乙烯)共聚物(ABS)合金的增容作用。运用红外光谱仪、毛细管流变仪和扫描电子显微镜等手段研究了SMAH增容的PA6/ABS合金的聚集态结构与性能。结果表明,PA6和ABS的简单共混体系的分散相容易聚集,断裂面呈岩石层状的脆性断裂形貌。而加入少量SMAH后的合金呈典型的"海-岛"结构,分散相分布均匀,断面呈现大量塑性变形的韧性断裂特征。

关 键 词:PA6  ABS  增容剂  相形态
收稿时间:2007-09-19
修稿时间:2007年9月19日

STUDY ON COMPATIBILIZATION OF STYRENE-MALEIC ANHYDRIDE(SMAH) TO POLYMER BLENDS OF POLYAMIDE-6 AND ACRYLONITRILE-BUTADIENE-STYRENE(ABS)
Zhang Kaizhou,Qin Shuhao,Yu Jie.STUDY ON COMPATIBILIZATION OF STYRENE-MALEIC ANHYDRIDE(SMAH) TO POLYMER BLENDS OF POLYAMIDE-6 AND ACRYLONITRILE-BUTADIENE-STYRENE(ABS)[J].Engineering Plastics Application,2007,35(12):22-25.
Authors:Zhang Kaizhou  Qin Shuhao  Yu Jie
Abstract:The compatibilization of SMAH on PA6/ABS blends were investigated. The morphology and mechanical properties of PA6/ABS/SMAH blends were investigated by SEM, FTIR and capillary viscometer. The results showed that the dispersed phase of PA6/ABS simple crossblend system congregated easily, the fracture surface exhibited rock sandwich, it was typical appearance of brittle fracture. By adding little amount of SMAH, the blends showed a typical "sea-island" morphology, and the dispersed phase dispersed uniformly, the fracture surface showed the characteristic of ductile fracture.
Keywords:PA6  ABS  compatibilizer  morphology
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