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过硫酸盐氧化碱浸低品位铜精矿提取钼
引用本文:王铁墨,刘志雄,李飞,李琴香,李光英,刘嘉琪,张敬森,段晓月.过硫酸盐氧化碱浸低品位铜精矿提取钼[J].矿冶工程,2022,42(3):104-107.
作者姓名:王铁墨  刘志雄  李飞  李琴香  李光英  刘嘉琪  张敬森  段晓月
作者单位:1.吉首大学 物理与机电工程学院, 湖南 吉首 416000; 2.河北保定地质实验测试中心, 河北 保定 071051; 3.吉首大学 湖南省2011计划锰锌钒工业技术协同创新中心, 湖南 吉首 416000; 4.矿物清洁生产与绿色功能材料开发湖南省重点实验室, 湖南 吉首 416000; 5.云南锡业股份有限公司卡房分公司, 云南 个旧 661000
基金项目:湖南省自然科学基金(2020JJ4507,2020JJ5456);;湖南省教育厅科学研究重点资助项目(19A413);
摘    要:以过硫酸钠为氧化剂, 在碳酸钠溶液中从低品位铜精矿中提取钼。运用单因素实验法, 探讨了搅拌速度、过硫酸钠和碳酸钠初始浓度、浸出时间、温度和液固比等因素对氧化碱浸提取钼的影响。结果表明,铜精矿氧化碱浸提取钼的优化条件为: 搅拌速度500 r/min, 浸出温度50 ℃, 碳酸钠初始浓度2.5 mol/L, 过硫酸钠初始浓度0.7 mol/L, 液固比10 mL/g, 浸出时间4.0 h, 在此条件下钼浸出率达97.10%。

关 键 词:铜精矿  氧化碱浸    过硫酸钠  氧化剂  
收稿时间:2021-12-27

Extraction of Molybdenum from Low-Grade Copper Concentrate by Persulfate Oxidation and Alkali Leaching
WANG Tie-mo,LIU Zhi-xiong,LI Fei,LI Qin-xiang,LI Guang-ying,LIU Jia-qi,ZHANG Jing-sen,DUAN Xiao-yue.Extraction of Molybdenum from Low-Grade Copper Concentrate by Persulfate Oxidation and Alkali Leaching[J].Mining and Metallurgical Engineering,2022,42(3):104-107.
Authors:WANG Tie-mo  LIU Zhi-xiong  LI Fei  LI Qin-xiang  LI Guang-ying  LIU Jia-qi  ZHANG Jing-sen  DUAN Xiao-yue
Abstract:With sodium persulfate as an oxidant, molybdenum was extracted from a low-grade copper concentrate in sodium carbonate solution. The effects of stirring speed, initial concentration of sodium persulfate and sodium carbonate, leaching time and temperature, as well as liquid-solid ratio on molybdenum extraction rate by oxidative alkaline leaching were investigated by performing single factor experiment. Results show that the leaching rate of molybdenum can reach 97.10%, after molybdenum is extracted from copper concentrate by using oxidative alkaline leaching at 50 ℃ for 4 h, with stirring speed at 500 r/min, initial concentration of sodium carbonate and sodium persulfate at 2.5 mol/L and 0.7 mol/L respectively, liquid-solid ratio at 10 mL/g.
Keywords:copper concentrate  oxidative alkaline leaching  molybdenum  sodium persulfate  oxidant  
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