Heat treatment temperature effect on the microstructure and optical properties of Dy2(WO4)3 powders |
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Authors: | Wenyan Zhang Chunhua Lu Yaru Ni Jianbin Song Wenjuan Huang Jing Tao Zhongzi Xu |
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Affiliation: | 1. College of Material Science and Engineering, Jinling Institute of Technology, Nanjing, 210009, China 2. State Key Laboratory of Materials-Orient Chemical Engineering, College of Material Science and Engineering, Nanjing University of Technology, Nanjing, 210009, China
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Abstract: | Dy2(WO4)3 powders were synthesized through liquid-phase reaction. The structure transformation of Dy2(WO4)3 powders were analyzed by differential scanning calorimetry (DSC), X-ray diffractometer (XRD) and Fourier transform infrared spectroscopy (FTIR). The optical absorption and photoluminescence properties were characterized by UV-vis-infra diffuse reflectance spectra and fluorescence spectra. The Dy2(WO4)3 host could absorb deep UV light and transfer the energy of UV light to Dy3+ ions, which convert the high-energy UV light to blue light (482 nm, 4 F 9/2→6 H 15/2) and yellow light (547 nm, 4 F 9/2→6 H 13/2). The Dy2(WO4)3 powders could also absorb near UV light and exhibit blue and yellow emissions near 482 and 547 nm, respectively. Heat treating promoted the crystallization and regulated the micro-structure of Dy2(WO4)3 hosts. The bands of W-Od anti-symmetric stretching vibration exhibited red shift with the increasing of sintering temperature. The W-Ob-W groups tended to combine with each other to form W-Oc-W groups after heat treating. These regulation of micro-structure had influence on the luminescent color of Dy2(WO4)3. The samples could emit yellow-green, white-yellow and white light under the excitation of 350 nm after being treated at 600, 800 and 1 000 °C, respectively. The prepared Dy2(WO4)3 powders have potential to act as UV absorber for solar cell to improve the conversion efficiency and also exhibit potential for white light LED. |
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