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X-RAY FLUORESCENCE SPECTRA ANALYSIS ON THE STRUCTURE AROUND Ti4+ OF BaO-SiO2-B2O3-TiO2 SYSTEM GLASSES
Authors:Song Xiaolan  Qu Yixin
Affiliation:SONG Xiaolan QU Yixin Central South University Beijing University of Chemical Technology Born in 1964;Assoc.Prof.;Dept.of Minerals Engineering.Central South University.Changsha 410083.China.
Abstract:The structure around Ti~(4 ) in Bao-SiO_2 -B_2O_3-TiO_2 had been studied by X-ray fluorescence spectra. The results show that the Ti~(4 ) mainly exists in the TiO_4] and enters the network of SiO_4]. TiO_4] has the tendency to change to TiO_6] with the increase of TiO_2 con-tent. When the TiO_2 content increases to about 20mol% the tendency reaches its maximum.
Keywords:titanium barium boronsilicate glasses  Ti~(4 ) structural state  X-ray fluorescence spectra analysis (XRF)
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