| SO3体系中碘催化甲烷的选择性氧化反应 |
| |
| 引用本文： | 李明华,洪林,陈立宇. SO3体系中碘催化甲烷的选择性氧化反应[J]. 当代化工, 2012, 41(4): 348-350,362 |
| |
| 作者姓名： | 李明华 洪林 陈立宇 |
| |
| 作者单位： | 1. 西北大学化工学院,陕西西安710069;第四军医大学化学教研室,陕西西安710032
2. 西北大学化工学院,陕西西安,710069 |
| |
| 摘 要： | 在SO3体系中,采用碘系列化合物作为催化剂进行甲烷部分氧化反应的研究.对催化剂进行筛选,考察反应工艺条件的影响,并对反应机理进行探讨.最终确定I2为最佳催化剂,反应的最优工艺条件为:催化剂0.099 mol·L-1,温度T=433K,初始压力P=4.0 MPa,搅拌速度500 r/min.该工艺条件下甲烷转化率可达63.57％,目的产物收率为52.6％,产物选择性82.74％.
|
| 关 键 词： | 甲烷 部分氧化 碘催化 SO3体系 |
Iodine-Catalyzed Partial Oxidation of Methane in SO3 system |
| |
| LI Ming-hua , HONG Lin , Chen Li-yu. Iodine-Catalyzed Partial Oxidation of Methane in SO3 system[J]. Contemporary Chemical Industry, 2012, 41(4): 348-350,362 |
| |
| Authors: | LI Ming-hua HONG Lin Chen Li-yu |
| |
| Affiliation: | 1(1.College of Chemical Engineering,Northwest University,Shaanxi Xi’an 710069,China; 2.Department of Chemistry,Fourth Military Medical University,Shaanxi Xi’an 710032,China) |
| |
| Abstract: | Using iodine compounds as catalyst,partial oxidation reaction of methane in SO3 system was studied.Catalysts were screened,and effect of process conditions were investigated,the reaction mechanism was discussed.The results show that the best catalyst is I2;the optimal process conditions are as follows: temperature is 433 K,amount of the catalyst is 0.099 mol?L?1,the initial pressure is 4 MPa,the stirring speed is 500 r/min.Under above conditions,the methane conversion rate is 63.57%,the yield of target product is 52.6%,and the product selectivity is 82.74%. |
| |
| Keywords: | Methane Partial oxidation Iodine catalysis SO3 system |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
