| 一种短氟链丙烯酸酯聚合物乳液制备及织物整理 |
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| 引用本文： | 成丽,李战雄,茅沈杰,郑满,杜丽萍,周绍强,蔡建和.一种短氟链丙烯酸酯聚合物乳液制备及织物整理[J].印染助剂,2011,28(10). |
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| 作者姓名： | 成丽 李战雄 茅沈杰 郑满 杜丽萍 周绍强 蔡建和 |
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| 作者单位： | 1. 苏州大学纺织与服装工程学院,江苏苏州,215021
2. 江苏省检验检疫科学技术研究院,江苏南京,210000 |
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| 基金项目： | 质检公益性行业科研专项“纺织品化学残留释放评估、快速检测及替代品技术的研究”(项目编号:200910013) |
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| 摘 要： | 以甲基丙烯酸十二氟庚酯、丙烯酸正丁酯、甲基丙烯酸丁酯为聚合单体,采用乳液共聚法制备了短氟链拒水拒油整理剂.FT-IR分析表明:3种单体发生了共聚,所制备的聚合物乳液平均粒径为76.9 nm,粒径分布相对均匀,乳液稳定性良好.探讨了聚合物氟含量对棉织物拒水拒油整理效果的影响,结果表明:随着聚合物氟含量增加,乳液用于整理织物的拒水拒油性也逐渐提高.聚合物氟含量34％时,该聚合物乳液整理后的棉织物拒水性可以达到4级,拒油性可达1级,对水接触角为130.5°.
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| 关 键 词： | 拒水拒油 整理 乳液共聚 棉织物 |
Preparation of emulsion by short-chain fluoroalkyl acrylate copolymer and its application on fabric finishing |
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| CHENG Li,LI Zhan-xiong,MAO Shen-jie,ZHENG Man,DU Li-ping,ZHOU Shao-qiang,CAI Jian-he.Preparation of emulsion by short-chain fluoroalkyl acrylate copolymer and its application on fabric finishing[J].Textile Auxiliaries,2011,28(10). |
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| Authors: | CHENG Li LI Zhan-xiong MAO Shen-jie ZHENG Man DU Li-ping ZHOU Shao-qiang CAI Jian-he |
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| Affiliation: | CHENG Li1,LI Zhan-xiong1,MAO Shen-jie1,ZHENG Man1,DU Li-ping1,ZHOU Shao-qiang2,CAI Jian-he2(1.College of Textile and Clothing Engineering,Soochow University,Suzhou 215021 China,2.Industrial Products Inspection Center of Jiangsu Exit-Entry Inspection & Quarantine Bureau of P.R.C.,Nanjing 210000,China) |
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| Abstract: | Short-chain water and oil repellent finishing agent was prepared by emulsion co-polymerization using hexafluoro-n-butul methacrylate,butyl acrylate and butyl methacrylateas as monomers.FT-IR analysis showed that there was copolymerization among the three acrylate monomers.The average particle size of the emulsion was about 76.9 nm,and the distribution was relatively uniform,which provided the emulsion with excellent stability.The effect of fluorine content in the polymer on the water-and oil-repellency was ... |
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| Keywords: | water and oil repellent finishing emulsion copolymerization cotton fabric |
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