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悬浮聚合法制备微球状压敏胶的研究
引用本文:李耀仓,马红霞,罗凡,魏凡,郭进标.悬浮聚合法制备微球状压敏胶的研究[J].中国胶粘剂,2011,20(12):38-41.
作者姓名:李耀仓  马红霞  罗凡  魏凡  郭进标
作者单位:武汉生物工程学院化学与环境工程系,湖北武汉,430415
基金项目:湖北省教育厅科学研究计划项目
摘    要:以丙烯酸-2-乙基己酯(2-EHA)、丙烯酸甲酯(MA)和丙烯酸(AA)为共聚单体,聚乙烯醇(PVA)为分散剂,过氧化苯甲酰(BPO)为引发剂,采用悬浮聚合法制备了可重复粘贴的微球状PSA(压敏胶).研究了水油比(即水与主单体质量比)、软硬单体质量比、分散剂种类和搅拌速率等对聚合物粒径及PSA性能的影响.结果表明:当水...

关 键 词:微球  压敏胶  悬浮聚合  粒径分布  丙烯酸酯

Study on preparing microsphere PSA by suspension polymerization method
Li Yaocang,Ma Hongxia,Luo Fan,Wei Fan,Guo Jinbiao.Study on preparing microsphere PSA by suspension polymerization method[J].China Adhesives,2011,20(12):38-41.
Authors:Li Yaocang  Ma Hongxia  Luo Fan  Wei Fan  Guo Jinbiao
Abstract:With 2-ethyl hexyl acrylate(2-EHA),methyl acrylate(MA) and acrylic acid(AA) as comonomers,polyvinyl alcohol(PVA) as dispersant,benzoyl peroxide(BPO) as initiator,the microsphere PSA(pressure sensitive adhesive) with repeatable bonding was prepared by suspension polymerization method.The influences of some factors such as mass ratio of water to oil,mass ratio of soft to hard monomers,dispersant types and mix round speed were investigated on polymer particle size and PSA's properties.The results showed that the corresponding microsphere PSA has good repeelable and repeatable bonding when mass ratios of water to oil and soft to hard monomers were 3∶1 and 6∶1 respectively,mass fraction of PVA-1788 was 1.00%,and mix round speed was 300 r/min.
Keywords:microsphere  pressure sensitive adhesive(PSA)  suspension polymerization  particle size distribution  acrylate
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