Rapid sintering protocol produces dense ceria‐based ceramics |
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| Authors: | Nimrod Yavo Asaf Nissenbaum Ellen Wachtel Tal‐El Shaul Orit Mendelson Giora Kimmel Sangtae Kim Igor Lubomirsky Ori Yeheskel |
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| Affiliation: | 1. Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot, Israel;2. Department of Chemistry, Nuclear Research Center Negev, Beer‐Sheva, Israel;3. Department of Nuclear Engineering and Institutes, Ben Gurion University, Beer‐Sheva, Israel;4. Department of Materials Engineering, UC Davis, Davis, California;5. Department of Materials, Nuclear Research Center Negev, Beer‐Sheva, Israel |
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| Abstract: | We report on a rapid sintering protocol, which optimizes the preparation of 0‐29 mol% Gd‐doped ceria ceramics with density ≥98% of the theoretical crystal lattice value. The starting material is a nanometer grain‐sized powder prepared by carbonate co‐precipitation and calcined with minimal agglomeration and loss of surface area. Slow (5°C/min) heating of the green‐body from 500°C to the optimum temperature of rapid sintering ( , dwell time <1 minute) followed by 20°C/min cooling to 1150°C with 6 minutes dwell time, produces maximum pellet density.  increases from 1300 to ~1500°C with increase in Gd‐content, while the average grain size in the maximally dense pellets, as determined by scanning electron microscopy, ranges between 600 nm and ~1 μm. For each doping level, the logarithm of the average grain size decreases linearly with 1/T1. By avoiding extended exposure to sintering temperatures, this protocol is expected to minimize undesirable Gd segregation. |
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| Keywords: | ceramics ceria nanometric powder pores sintering |
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, dwell time <1 minute) followed by 20°C/min cooling to 1150°C with 6 minutes dwell time, produces maximum pellet density. 
increases from 1300 to ~1500°C with increase in Gd‐content, while the average grain size in the maximally dense pellets, as determined by scanning electron microscopy, ranges between 600 nm and ~1 μm. For each doping level, the logarithm of the average grain size decreases linearly with 1/T1. By avoiding extended exposure to sintering temperatures, this protocol is expected to minimize undesirable Gd segregation.