Kinetic studies of dyes sorption from aqueous solutions onto the strongly basic anion-exchanger Lewatit MonoPlus M-600 |
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Authors: | Monika Wawrzkiewicz Zbigniew Hubicki |
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Affiliation: | aDepartment of Inorganic Chemistry, Faculty of Chemistry, Maria Curie – Sklodowska University, 20-031 Lublin, M. Sklodowska Sq. 2, Poland |
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Abstract: | The sorption of Tartrazine, Allura Red, Sunset Yellow and Indigo Carmine from aqueous solutions onto the strongly basic anion-exchanger (Lewatit MonoPlus M-600) of dimethylethanolamine functional groups and styrene–divinylbenzene matrix was investigated. The experimental data obtained at 50, 100, 200, 300 and 500 mg/dm3 initial concentrations at 20 °C were applied to the pseudo-first order, pseudo-second order and Weber–Morris kinetic models. The calculated sorption capacities (q1,cal) and the rate constant of the first-order adsorption (k1) were determined. The pseudo-second order kinetic constants (k2) and capacities (q2,cal) were calculated from the plots of t/qt vs. t, 1/qt vs. 1/t, 1/t vs. 1/qt, qt/t vs. qt and 1/q2 − qt vs. t for type 1, type 2, type 3, type 4 and type 5 of the pseudo-second order expression, respectively. |
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Keywords: | Dyes Anion-exchanger Kinetics Sorption Pseudo-second order Adsorption |
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