| 金属卟啉催化烷烃氧化研究及工业应用进展 |
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| 引用本文： | 刘小秦.金属卟啉催化烷烃氧化研究及工业应用进展[J].合成纤维工业,2003,26(3):35-37. |
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| 作者姓名： | 刘小秦 |
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| 作者单位： | 中国石化股份公司巴陵分公司,湖南,岳阳,414003 |
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| 摘 要： | 介绍了国内外金属卟啉及金属卟啉催化烷烃氧化的研究情况 ,对其催化氧化环己烷生产环己酮工业应用进行了连续性研究 ,实验表明 :环己烷在 14 3～ 14 7℃ ,0 .8～ 0 .9MPa和金属卟啉催化条件下 ,环己烷转化率达 7%左右时 ,环己醇、环己酮和环己基过氧化氢的选择性可达到 87%以上 ,其中环己醇和环己酮占75 %以上
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| 关 键 词： | 金属卟啉 催化 氧化 环己烷 环己酮 |
| 文章编号： | 1001-0041(2003)03-0035-03 |
| 修稿时间： | 2002年11月29 |
Research and industrial application of metal porphyrin- catalyzed alkane oxidation |
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| Liu Xiaoqin.Research and industrial application of metal porphyrin- catalyzed alkane oxidation[J].China Synthetic Fiber Industry,2003,26(3):35-37. |
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| Authors: | Liu Xiaoqin |
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| Abstract: | The research situation of metal porphyrin and its catalysis in alkane oxidation was introduced. The consecutive experiments were conducted to study cyclohexanone production from cyclohexane with metal porphyrin catalyzing the oxidation. The results showed that the conversion ratio of cyclohexane reached about 7% at the catalytic conditions of 143～147℃ and 0.8～ 0.9 MPa, and the selective ratio of cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide was above 87% in which cyclohexanol and cyclohexanone was above 75%. |
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| Keywords: | porphyrin metal catalysis oxidation cyclohexane cyclohexanone |
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