| Mn(C_2Cl_3O_2)Cl(C_(12)H_8N_2)_2的合成、表征及其纳米晶体参数计算 |
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| 引用本文： | 陈洪,娄银斌,胡波,陈亮,王贤文,陈敬中.Mn(C_2Cl_3O_2)Cl(C_(12)H_8N_2)_2的合成、表征及其纳米晶体参数计算[J].中国粉体技术,2008,14(2):18-21. |
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| 作者姓名： | 陈洪 娄银斌 胡波 陈亮 王贤文 陈敬中 |
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| 作者单位： | 中国地质大学材料科学与化学工程学院,湖北,武汉,430074 |
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| 摘 要： | 以Cl3CCOOH、1,10-菲罗啉为配体,以MnCl2·4H2O为金属离子盐,通过溶液蒸发法合成了具有纳米级金属骨架的三元配合物Mn(C2Cl3O2)Cl(C12H8N2)2。通过元素分析、红外光谱、X单晶衍射测得配合物属于单斜晶系,其空间群为P21/c,a=1.8155nm,b=1.0638nm,c=1.4685nm,β=112.9°,z=4,V=2.6110nm3。通过纳米化计算的方法,计算出总晶胞数、总原子数、及表面参数随粒径变化的关系,得出Mn(C2Cl3O2)Cl(C12H8N2)2最佳纳米化尺度为115nm。
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| 关 键 词： | Mn(C_2Cl_3O_2)Cl(C_(12)H_8N_2)_2配合物 晶体 晶胞参数 纳米晶体 |
| 文章编号： | 1008-5548(2008)02-0018-04 |
| 修稿时间： | 2007年6月12日 |
Synthesis, Structure and Calculation of Nano-crystalline Parameters Complex of Mn(C2Cl3O2)CI(C12H8N2)2 |
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| Chen Hong,Lou Yinbing,Hu Bo,Chen Liang,Wang Xianwen,Chen Jingzhong.Synthesis, Structure and Calculation of Nano-crystalline Parameters Complex of Mn(C2Cl3O2)CI(C12H8N2)2[J].China Powder Science and Technology,2008,14(2):18-21. |
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| Authors: | Chen Hong Lou Yinbing Hu Bo Chen Liang Wang Xianwen Chen Jingzhong |
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| Abstract: | The trinuclear zinc(II) complex Mn(C2Cl3O2)Cl(C12H8N2)2 was synthesized and structurally characterized by single crystal X-ray diffraction method. The data showed that the Mn(C2Cl3O2)Cl(C12H8N2)2 complex belonged to the monoclinic crystal system, the crystal data was a=1.815 5 nm,b=1.063 8 nm,c=1.468 5 nm, β=112.9°, z=4,V=2.611 0 nm3. On the basis of the crystal structure of the title compound,the crystal cell numbers, atomicity, surface layer atomicity and its proportion were assumed. And the computation discussion to turning compounds into nano-meter particle was theoretically carried on. The optimum dimension of its nano- particle is theroretically assured to be about 115 nm. |
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| Keywords: | Mn(C_2Cl_3O_2)Cl(C_(12)H_8N_2)_2 complex crystal crystal cell number nano-crystalline |
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