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Surface properties of ZSM-5 modified by phosphorus
Authors:B Viswanathan  Alex C Pulikottil
Affiliation:(1) Department of Chemistry, Indian Institute of Technology, 600036 Madras, India
Abstract:Phosphorus modification of ZSM-5 leads to extra framework P5+ and probably incorporation of +3 valence state of P in the framework. The resulting system has increased Brønsted acidity. Theoretical calculations also favour the postulate that phosphorus in +3 valence state can be incorporated into the lattice.
Keywords:ZSM-5  pyridine adsorption  Xagr method" target="_blank">gif" alt="agr" align="BASELINE" BORDER="0"> method  phosphorus valence state
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