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烷基磷酸酯钾盐乳化稳定性研究
引用本文:戴伊萍,杨毓莹,舒建生,沙晓祥,李干佐,朱长德,牟建海. 烷基磷酸酯钾盐乳化稳定性研究[J]. 精细化工, 2004, 21(Z1): 32-34
作者姓名:戴伊萍  杨毓莹  舒建生  沙晓祥  李干佐  朱长德  牟建海
作者单位:1. 上海石油化工股份有限公司,科技开发公司,上海,200540
2. 山东大学,山东,济南,250100
摘    要:烷基磷酸酯钾盐乳液的稳定性极大地影响其作为阴离子表面活性剂的应用。该文应用胶体化学理论,从乳状液稳定性原理出发,对烷基磷酸酯钾盐的乳化工艺进行了研究,采取初生皂法乳化工艺,乳化反应温度50~60℃,反应时间10~20min,控制反应产物的pH=10±1,可得到含有溶致液晶的、类似双连续型的稳定的烷基磷酸酯钾盐乳液。

关 键 词:烷基磷酸酯钾盐  乳状液  稳定性
文章编号:1003-5214(2004)S0-0032-03
修稿时间:2003-10-30

Emulsion Stability of Potassium Alkyl Phosphate
DAI Yi-ping,YANG Yu-ying,SHU Jian-sheng,SHA Xiao-xiang,LI Gan-zuo,ZHU Chang-de,MU Jian-hai. Emulsion Stability of Potassium Alkyl Phosphate[J]. Fine Chemicals, 2004, 21(Z1): 32-34
Authors:DAI Yi-ping  YANG Yu-ying  SHU Jian-sheng  SHA Xiao-xiang  LI Gan-zuo  ZHU Chang-de  MU Jian-hai
Affiliation:DAI Yi-ping~1,YANG Yu-ying~1,SHU Jian-sheng~1,SHA Xiao-xiang~1,LI Gan-zuo~2,ZHU Chang-de~2,MU Jian-hai~2
Abstract:Emulsions of potassium alkyl phosphate are used as anionic surfactants.As they are thermodynamically instable systems,their applications are usually limited.Using the "new soap" method,the emulsification technique of potassium alkyl phosphate was studied.Thus,at 50~60 ℃,reacting for 10~20 min and controlling pH of the product at 10±1,stable emulsions of potassium alkyl phosphate containing liquid crystal and in a state similar to bicontinous phase are prepared.
Keywords:potassium alkyl phosphate  emulsion  stability
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