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填料塔中碳酸钾/哌嗪混合吸收液脱除CO2的体积传质系数
引用本文:骆培成,焦真,张志炳. 填料塔中碳酸钾/哌嗪混合吸收液脱除CO2的体积传质系数[J]. 化工学报, 2005, 56(1): 53-57
作者姓名:骆培成  焦真  张志炳
作者单位:南京大学化工系,江苏,南京,210093;南京大学化工系,江苏,南京,210093;南京大学化工系,江苏,南京,210093
基金项目:国家“985”工程资助项目~~
摘    要:The process of removing dilute CO2 from air by using me mixtures of K2CO3 and piperazine (PZ) was conducted in a random packed tower at 25℃. The results showed that PZ increased the absorption rate of CO2 into aqueous K2 CO3 much more effectively than MEA or DEA. The volumetric overall mass transfer coefficient (KGa) of dilute CO2 absorption into K2CO3/PZ was measured. The KGa value was evaluated over the ranges of main operating variables: the concentration of CO2 in inlet gas, gas flow rate, liquid loading, CO2 loading in liquid phase, and the concentrations of K2CO3 and PZ. The test showed that KGa could be remarkably improved by increasing liquid loading and the concentration of PZ, and decreasing the concentration of CO2 in inlet gas, as well as the gas flow rate and CO2 loading in liquid phase.

关 键 词:二氧化碳  碳酸钾  哌嗪  填料塔  体积总传质系数
文章编号:0438-1157(2005)01-0053-05
收稿时间:2004-01-07
修稿时间:2004-8-17 

Volumetric mass transfer coefficients of dilute CO2 absorption into mixtures of potassium carbonate and piperazine in packed column
LUO Peicheng,JIAO Zhen,Zhang Zhibing. Volumetric mass transfer coefficients of dilute CO2 absorption into mixtures of potassium carbonate and piperazine in packed column[J]. Journal of Chemical Industry and Engineering(China), 2005, 56(1): 53-57
Authors:LUO Peicheng  JIAO Zhen  Zhang Zhibing
Abstract:The process of removing dilute CO2 from air by using the mixtures of K2CO3 and piperazine (PZ) was conducted in a random packed tower at 25 ℃.The results showed that PZ increased the absorption rate of CO2 into aqueous K2CO3 much more effectively than MEA or DEA. The volumetric overall mass transfer coefficient (KGa) of dilute CO2 absorption into K2CO3/PZ was measured.The KGa value was evaluated over the ranges of main operating variables: the concentration of CO2 in inlet gas, gas flow rate, liquid loading, CO2 loading in liquid phase,and the concentrations of K2CO3 and PZ. The test showed that KGa could be remarkably improved by increasing liquid loading and the concentration of PZ, and decreasing the concentration of CO2 in inlet gas, as well as the gas flow rate and CO2 loading in liquid phase.
Keywords:carbon dioxide  potassium carbonate  piperazine  packed column  volumetric overall mass transfer coefficient
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